SOLUBILITIES OF NaCl AND KCl IN THE MIXED SOLVENTS OF CH3OH-DMF AND CH3OH-DMSO AT 278,288,298,303 AND 313K | |
Li Zhifen ; Huang Yining ; Wang Lei ; Xu Yihui ; Liu Ruilin | |
刊名 | 物理化学学报
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1988 | |
DOI | 10.3866/PKU.WHXB19880212 |
英文摘要 | Solubilities of KCl and NaCl in binary mixed solvents of CH3OH-DMF ad CH3OH-DMSO with mole fraction of components from 0 to 1 were measured at 288,303,313K for KCl and 278,288,298,303 and 313K for NaCl. A plot of solubility of KCl and NaCl vs composition of solvent shows a maximum. The coefficient of solubility with temperature for KCl is positive and for NaCl is negative. The transfer free energy and entropy of KCl and NaCl from pure methanol to mixed solvents were evaluated from the measurements, thus the structure property of solution, the effect of salt on it, the ionic solvation and the tendentiousness of solution were discussed preliminarily.; http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000207571300011&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=8e1609b174ce4e31116a60747a720701 ; Chemistry, Physical; SCI(E); 0; ARTICLE; 2; 177-181; 4 |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://ir.pku.edu.cn/handle/20.500.11897/390257] ![]() |
专题 | 化学与分子工程学院 |
推荐引用方式 GB/T 7714 | Li Zhifen,Huang Yining,Wang Lei,et al. SOLUBILITIES OF NaCl AND KCl IN THE MIXED SOLVENTS OF CH3OH-DMF AND CH3OH-DMSO AT 278,288,298,303 AND 313K[J]. 物理化学学报,1988. |
APA | Li Zhifen,Huang Yining,Wang Lei,Xu Yihui,&Liu Ruilin.(1988).SOLUBILITIES OF NaCl AND KCl IN THE MIXED SOLVENTS OF CH3OH-DMF AND CH3OH-DMSO AT 278,288,298,303 AND 313K.物理化学学报. |
MLA | Li Zhifen,et al."SOLUBILITIES OF NaCl AND KCl IN THE MIXED SOLVENTS OF CH3OH-DMF AND CH3OH-DMSO AT 278,288,298,303 AND 313K".物理化学学报 (1988). |
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