Polyoxometalates Pillared Hydrotalcite : Synthesis and Catalysis in Transesterif ication of Dimethyl Carbonate and Phenol

CORC > 青岛生物能源与过程研究所 > 中国科学院青岛生物能源与过程研究所 > 生物制氢与沼气团队

	Polyoxometalates Pillared Hydrotalcite : Synthesis and Catalysis in Transesterif ication of Dimethyl Carbonate and Phenol
	LUO Sheng2jun (罗生军) ; CHI Ying2nan (迟瑛楠) ; HU Chang2wen (胡长文)
刊名	Journal of Beijing Institute of Technology
	2009
卷号	2 期号:2 页码:229-232
关键词	polyoxometalates hydrotalcite transesterification diphenyl carbonate
ISSN号	ISSN :1004-0579
中文摘要	The salts of para2tungstic and para2molybdic were heterogenized for their effective use as solid catalysts in the transesterification reaction of dimethyl carbonate and phenol by inserting them between the layers of Mg2Al-hydrotalcite. These catalysts were characterized by FT-IR spectra and X-ray powder diffraction. Polyoxometalates (POMs) clusters were intercalated into the interlayer of layered double hydroxide (LDH) via anion exchange with organic acid precursor in Mg2Al-LDH, and the integrity of the clusters [W7O24]6 – and [Mo7O24]6 - was maintained. The intercalated para-molybdic cluster showed high catalytic activity and reusability in the transesterification under mild reaction conditions. When the reaction was carried out at 180 ℃, with a molar ratio of phenol to DMC of 1∶1 , a reaction time 10 h , and a catalyst amount 1%(wt) , the conversion of phenol was 1010 % , the selectivities of diphenyl carbonate and methyl phenyl carbonate were 1017 % and 8611 % , respectively.
学科主题	生物制氢与沼气
收录类别	CSCD
语种	英语
公开日期	2011-09-09
内容类型	期刊论文
源URL	[http://ir.qibebt.ac.cn//handle/337004/492]
专题	青岛生物能源与过程研究所_生物制氢与沼气团队
推荐引用方式 GB/T 7714	LUO Sheng2jun ,CHI Ying2nan ,HU Chang2wen . Polyoxometalates Pillared Hydrotalcite : Synthesis and Catalysis in Transesterif ication of Dimethyl Carbonate and Phenol[J]. Journal of Beijing Institute of Technology,2009,2(2):229-232.
APA	LUO Sheng2jun ,CHI Ying2nan ,&HU Chang2wen .(2009).Polyoxometalates Pillared Hydrotalcite : Synthesis and Catalysis in Transesterif ication of Dimethyl Carbonate and Phenol.Journal of Beijing Institute of Technology,2(2),229-232.
MLA	LUO Sheng2jun ,et al."Polyoxometalates Pillared Hydrotalcite : Synthesis and Catalysis in Transesterif ication of Dimethyl Carbonate and Phenol".Journal of Beijing Institute of Technology 2.2(2009):229-232.