Conversion of Aromatic Amino into Trifluoromethyl Groups through a   Sandmeyer-Type Transformation

doi:10.1055/s-0033-1338659

CORC > 北京大学 > 化学与分子工程学院

	Conversion of Aromatic Amino into Trifluoromethyl Groups through a Sandmeyer-Type Transformation
	Wang, Xi ; Xu, Yan ; Zhou, Yujing ; Zhang, Yan ; Wang, Jianbo
刊名	synthesis stuttgart
	2014
关键词	trifluoromethylation aromatic amines diazonium salts silver Sandmeyer reaction PALLADIUM-CATALYZED TRIFLUOROMETHYLATION SILVER-MEDIATED TRIFLUOROMETHYLATION BORONIC ACIDS ARYLBORONIC ACIDS SYNTHETIC METHODS DIAZONIUM SALTS ALKYL NITRITES ARYL STANNANES ARENES PERFLUOROALKYLATION
DOI	10.1055/s-0033-1338659
英文摘要	A novel strategy for aromatic trifluoromethylation by converting amino into trifluoromethyl groups via a Sandmeyer-type reaction is reported. The transformation involves diazotization of the aromatic amines with tert-butyl nitrite and hydrochloric acid to form aryldiazonium chlorides, followed by trifluoromethylation with trifluoromethylsilver at low temperature. Various readily available aromatic amines are smoothly converted under mild conditions.; http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000340875300004&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=8e1609b174ce4e31116a60747a720701 ; Chemistry, Organic; SCI(E); 4; ARTICLE; wangjb@pku.edu.cn; 16; 2143-2148; 46
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/388656]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Wang, Xi,Xu, Yan,Zhou, Yujing,et al. Conversion of Aromatic Amino into Trifluoromethyl Groups through a Sandmeyer-Type Transformation[J]. synthesis stuttgart,2014.
APA	Wang, Xi,Xu, Yan,Zhou, Yujing,Zhang, Yan,&Wang, Jianbo.(2014).Conversion of Aromatic Amino into Trifluoromethyl Groups through a Sandmeyer-Type Transformation.synthesis stuttgart.
MLA	Wang, Xi,et al."Conversion of Aromatic Amino into Trifluoromethyl Groups through a Sandmeyer-Type Transformation".synthesis stuttgart (2014).