Mechanistic comparison of beta-H elimination, beta-OH elimination, and   nucleophilic displacement reactions of beta-hydroxy alkyl rhodium   porphyrin complexes

doi:10.1039/c0dt01146k

CORC > 北京大学 > 化学与分子工程学院

	Mechanistic comparison of beta-H elimination, beta-OH elimination, and nucleophilic displacement reactions of beta-hydroxy alkyl rhodium porphyrin complexes
	Wu, Bing ; Zhang, Jiadi ; Yun, Lin ; Fu, Xuefeng
刊名	dalton transactions
	2011
关键词	BOND-DISSOCIATION ENERGIES CO-C BOND HYDRIDE ELIMINATION REDUCTIVE ELIMINATION ALKOXIDE COMPLEXES CATALYZED OXIDATION INSERTION ALKENES DECOMPOSITION ACTIVATION
DOI	10.1039/c0dt01146k
英文摘要	This article reports on kinetic studies for three alternate pathways, including beta-hydrogen elimination, beta-hydroxy elimination, and intramolecular nucleophilic displacement reactions, for rhodium porphyrin beta-hydroxy alkyl reactions in water and DMSO to form ketone, alkene, and epoxide, respectively. Comparisons of activation parameters for these processes indicate that the beta-hydroxy elimination process has the lowest activation enthalpy in water, but the intramolecular nucleophilic displacement pathway predominates in DMSO.; http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000287665000020&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=8e1609b174ce4e31116a60747a720701 ; Chemistry, Inorganic & Nuclear; SCI(E); EI; PubMed; 7; ARTICLE; 10; 2213-2217; 40
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/344030]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Wu, Bing,Zhang, Jiadi,Yun, Lin,et al. Mechanistic comparison of beta-H elimination, beta-OH elimination, and nucleophilic displacement reactions of beta-hydroxy alkyl rhodium porphyrin complexes[J]. dalton transactions,2011.
APA	Wu, Bing,Zhang, Jiadi,Yun, Lin,&Fu, Xuefeng.(2011).Mechanistic comparison of beta-H elimination, beta-OH elimination, and nucleophilic displacement reactions of beta-hydroxy alkyl rhodium porphyrin complexes.dalton transactions.
MLA	Wu, Bing,et al."Mechanistic comparison of beta-H elimination, beta-OH elimination, and nucleophilic displacement reactions of beta-hydroxy alkyl rhodium porphyrin complexes".dalton transactions (2011).