Oxidation of C-H bonds to C=O bonds by O-2 only or N-oxides and DMSO: synthesis of Delta(1)-bipyrrolinones and pyrrolino[3,2-b]pyrrolinones from 2,6-diazasemibullvalenes | |
Zhang, Shaoguang ; Zhan, Ming ; Luo, Qian ; Zhang, Wen-Xiong ; Xi, Zhenfeng | |
刊名 | chemical communications
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2013 | |
关键词 | MOLECULAR-OXYGEN SINGLET OXYGEN AZIRIDINES DIMETHOXYCARBENE DERIVATIVES EFFICIENT CHEMISTRY CARBONYL KETONES |
DOI | 10.1039/c3cc43061h |
英文摘要 | 2,6-Diazasemibullvalenes (NSBVs) readily reacted with oxygen under mild conditions, affording Delta(1)-bipyrrolinones via C-N bond cleavage and C-H bond oxidation. Pyrrolino[3,2-b]pyrrolinone derivatives were efficiently generated when NSBVs were treated with N-oxides in the presence of Lewis acids. Delta(1)-Bipyrrolinones thus obtained could be readily transformed into other heterocycles.; http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000320332500010&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=8e1609b174ce4e31116a60747a720701 ; Chemistry, Multidisciplinary; SCI(E); PubMed; 8; ARTICLE; 55; 6146-6148; 49 |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://ir.pku.edu.cn/handle/20.500.11897/342676] ![]() |
专题 | 化学与分子工程学院 |
推荐引用方式 GB/T 7714 | Zhang, Shaoguang,Zhan, Ming,Luo, Qian,et al. Oxidation of C-H bonds to C=O bonds by O-2 only or N-oxides and DMSO: synthesis of Delta(1)-bipyrrolinones and pyrrolino[3,2-b]pyrrolinones from 2,6-diazasemibullvalenes[J]. chemical communications,2013. |
APA | Zhang, Shaoguang,Zhan, Ming,Luo, Qian,Zhang, Wen-Xiong,&Xi, Zhenfeng.(2013).Oxidation of C-H bonds to C=O bonds by O-2 only or N-oxides and DMSO: synthesis of Delta(1)-bipyrrolinones and pyrrolino[3,2-b]pyrrolinones from 2,6-diazasemibullvalenes.chemical communications. |
MLA | Zhang, Shaoguang,et al."Oxidation of C-H bonds to C=O bonds by O-2 only or N-oxides and DMSO: synthesis of Delta(1)-bipyrrolinones and pyrrolino[3,2-b]pyrrolinones from 2,6-diazasemibullvalenes".chemical communications (2013). |
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