Oxidation of C-H bonds to C=O bonds by O-2 only or N-oxides and DMSO:   synthesis of Delta(1)-bipyrrolinones and pyrrolino[3,2-b]pyrrolinones   from 2,6-diazasemibullvalenes

doi:10.1039/c3cc43061h

CORC > 北京大学 > 化学与分子工程学院

	Oxidation of C-H bonds to C=O bonds by O-2 only or N-oxides and DMSO: synthesis of Delta(1)-bipyrrolinones and pyrrolino[3,2-b]pyrrolinones from 2,6-diazasemibullvalenes
	Zhang, Shaoguang ; Zhan, Ming ; Luo, Qian ; Zhang, Wen-Xiong ; Xi, Zhenfeng
刊名	chemical communications
	2013
关键词	MOLECULAR-OXYGEN SINGLET OXYGEN AZIRIDINES DIMETHOXYCARBENE DERIVATIVES EFFICIENT CHEMISTRY CARBONYL KETONES
DOI	10.1039/c3cc43061h
英文摘要	2,6-Diazasemibullvalenes (NSBVs) readily reacted with oxygen under mild conditions, affording Delta(1)-bipyrrolinones via C-N bond cleavage and C-H bond oxidation. Pyrrolino[3,2-b]pyrrolinone derivatives were efficiently generated when NSBVs were treated with N-oxides in the presence of Lewis acids. Delta(1)-Bipyrrolinones thus obtained could be readily transformed into other heterocycles.; http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000320332500010&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=8e1609b174ce4e31116a60747a720701 ; Chemistry, Multidisciplinary; SCI(E); PubMed; 8; ARTICLE; 55; 6146-6148; 49
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/342676]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Zhang, Shaoguang,Zhan, Ming,Luo, Qian,et al. Oxidation of C-H bonds to C=O bonds by O-2 only or N-oxides and DMSO: synthesis of Delta(1)-bipyrrolinones and pyrrolino[3,2-b]pyrrolinones from 2,6-diazasemibullvalenes[J]. chemical communications,2013.
APA	Zhang, Shaoguang,Zhan, Ming,Luo, Qian,Zhang, Wen-Xiong,&Xi, Zhenfeng.(2013).Oxidation of C-H bonds to C=O bonds by O-2 only or N-oxides and DMSO: synthesis of Delta(1)-bipyrrolinones and pyrrolino[3,2-b]pyrrolinones from 2,6-diazasemibullvalenes.chemical communications.
MLA	Zhang, Shaoguang,et al."Oxidation of C-H bonds to C=O bonds by O-2 only or N-oxides and DMSO: synthesis of Delta(1)-bipyrrolinones and pyrrolino[3,2-b]pyrrolinones from 2,6-diazasemibullvalenes".chemical communications (2013).