Group exchange between ketones and carboxylic acids through directing group assisted Rh-catalyzed reorganization of carbon skeletons

doi:10.1021/ja512003d

CORC > 北京大学 > 化学与分子工程学院

	Group exchange between ketones and carboxylic acids through directing group assisted Rh-catalyzed reorganization of carbon skeletons
	Lei, Zhi-Quan ; Pan, Fei ; Li, Hu ; Li, Yang ; Zhang, Xi-Sha ; Chen, Kang ; Wang, Xin ; Li, Yu-Xue ; Sun, Jian ; Shi, Zhang-Jie
刊名	journal of the american chemical society
	2015
DOI	10.1021/ja512003d
英文摘要	The Rh(I)-catalyzed direct reorganization of organic frameworks and group exchanges between carboxylic acids and aryl ketones was developed with the assistance of directing group. Biaryls, alkenylarenes, and alkylarenes were produced in high efficiency from aryl ketones and the corresponding carboxylic acids by releasing the other molecule of carboxylic acids and carbon monoxide. A wide range of functional groups were well compatible. The exchanges between two partners were proposed to take place on the Rh-(III) center of key intermediates, supported by experimental mechanistic studies and computational calculations. The transformation unveiled the new catalytic pathway of the group transfer of two organic molecules. ? 2015 American Chemical Society.; SCI(E); EI; 0; ARTICLE; liyuxue@mail.sioc.ac.cn; sunjian@cib.ac.cn; zshi@pku.edu.cn; 15; 5012-5020; 137
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/328315]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Lei, Zhi-Quan,Pan, Fei,Li, Hu,et al. Group exchange between ketones and carboxylic acids through directing group assisted Rh-catalyzed reorganization of carbon skeletons[J]. journal of the american chemical society,2015.
APA	Lei, Zhi-Quan.,Pan, Fei.,Li, Hu.,Li, Yang.,Zhang, Xi-Sha.,...&Shi, Zhang-Jie.(2015).Group exchange between ketones and carboxylic acids through directing group assisted Rh-catalyzed reorganization of carbon skeletons.journal of the american chemical society.
MLA	Lei, Zhi-Quan,et al."Group exchange between ketones and carboxylic acids through directing group assisted Rh-catalyzed reorganization of carbon skeletons".journal of the american chemical society (2015).