Implicit characteristic parameter of a programmed temperature retention index database | |
Sun, YL ; Huang, AJ ; Wang, QQ ; Wei, P | |
刊名 | 中国科学b辑 化学英文版
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1996 | |
关键词 | programmed temperature gas chromatography programmed temperature retention index database reproductibility influence of column materials GAS-CHROMATOGRAPHY IDENTIFICATION HYDROCARBONS COLUMNS SYSTEM |
英文摘要 | In a programmed temperature retention index (PTRI) database, there exists a characteristic parameter rt(0)/beta that can be calculated if the experimental parameters are clearly given. This characteristic parameter can be used to flexibly reproduce the original PTRI data under chromatographic conditions different from those originally given. As this characteristic parameter is not explicitly given, it is suggested to name this parameter as the implicit characteristic parameter (ICP) of a PTRI database. The ICP in White's PTRI database was easily found and used satisfactorily to reproduce PTRI of some test compounds using either a Hewlett-Packard ultra-performance OV-1 column or a self-coated OV-1 column. The reproduction of PTRI could not be realized on columns of different materials. The fact several PTRI databases measured on glass capillary columns could not satisfactorily be reproduced on fused silical column is explained.; Chemistry, Multidisciplinary; SCI(E); 1; 3; 308-317; 39 |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://ir.pku.edu.cn/handle/20.500.11897/313466] ![]() |
专题 | 化学与分子工程学院 |
推荐引用方式 GB/T 7714 | Sun, YL,Huang, AJ,Wang, QQ,et al. Implicit characteristic parameter of a programmed temperature retention index database[J]. 中国科学b辑 化学英文版,1996. |
APA | Sun, YL,Huang, AJ,Wang, QQ,&Wei, P.(1996).Implicit characteristic parameter of a programmed temperature retention index database.中国科学b辑 化学英文版. |
MLA | Sun, YL,et al."Implicit characteristic parameter of a programmed temperature retention index database".中国科学b辑 化学英文版 (1996). |
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