聚{11-[(4&apos;-正庚氧基-4-联苯基)羰基]氧-1-十一炔}的相结构与相转变

CORC > 北京大学 > 化学与分子工程学院

	聚{11-[(4'-正庚氧基-4-联苯基)羰基]氧-1-十一炔}的相结构与相转变; PHASE TRANSITIONS AND STRUCTURES OF POLY(11-{ [ (4'-HEPTOXY-4-BIPHENYLYL)CARBONYL]OXY} -1-UNDECYNE)
	余振强 ; 刘嘉浩 ; 朱才镇 ; 陈尔强 ; 唐本忠 ; LAM Jacky Wing Yip
刊名	高分子学报
	2010
关键词	聚炔液晶相结构相转变X-射线衍射 Polyacetylene Liquid crystal Phase structure Phase transition X-ray diffraction
英文摘要	采用示差扫描量热法(DSC)、一维(1D)、二维(2D)广角X-射线衍射(WAXD)和偏光显微镜(PLM)等研究手段对聚{11-[(4'-正庚氧基-4-联苯基)羰基]氧-1-十一炔}(PA-9,7)的本体相转变和相结构进行研究,并采用分子动力学方法对相结构进行模拟.结果表明,样品的相转变为近晶B相(SmB)(→)近晶A相(SmA)(→)各向同性态(Iso).在近晶B相中,侧链在层状结构中排列成具有六次对称性的准长程有序结构.; A side chain liquid crystalline (LC) polyacetylene with long spacers, namely, poly (11-{[(4'-heptoxy-4-biphenylyl) carbonyl] oxy}-1-undecyne) (PA-9, 7), with high trans configuration was synthesized and the phase structures and transition behaviors were studied using differential scanning calorimetry (DSC), one- and two-dimensional (1D and 2D) wide-angle X-ray diffraction (WAXD) and polarized light microscopy (PLM). The molecular packing was simulated by Materials Studio (Accelrys) and the energy was minimized using Smart Minimizer incorporated in the Discover Molecular Simulation Program. The long spacer of PA-9,7 decouples the side chain mesogen and the rigid polyacetylene backbone and results in the formation of smectic phases, but not the frustrated highly ordered smectic phase of its cousin with short spacer. DSC and 1D WAXD results showed that the sample possesses two LC phases. Based on structural results obtained from 2D WAXD experiments on oriented sample, the phase structures of PA-9,7 were determined to be smectic B phase (SmB) below 70 degrees C, smectic A phase (SmA) in the temperature ranges 70 similar to 118 degrees C and isotropic phase (Iso) higher than 118 degrees C. For the SmB phase, the side chains can pack into the pseudo-long range order with hexagonal symmetry within the smectic layers. The LC phase transition of PA-9,7 follows the sequence of SmB <-> SmA <-> Iso.; 国家自然科学基金; 广东省自然科学基金; 深圳大学青年基金; http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000279101000023&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=8e1609b174ce4e31116a60747a720701 ; SCI(E); 中文核心期刊要目总览(PKU); 中国科技核心期刊(ISTIC); 中国科学引文数据库(CSCD); 1; 6; 759-764
语种	中文
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/313199]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	余振强,刘嘉浩,朱才镇,等. 聚{11-[(4'-正庚氧基-4-联苯基)羰基]氧-1-十一炔}的相结构与相转变, PHASE TRANSITIONS AND STRUCTURES OF POLY(11-{ [ (4'-HEPTOXY-4-BIPHENYLYL)CARBONYL]OXY} -1-UNDECYNE)[J]. 高分子学报,2010.
APA	余振强,刘嘉浩,朱才镇,陈尔强,唐本忠,&LAM Jacky Wing Yip.(2010).聚{11-[(4'-正庚氧基-4-联苯基)羰基]氧-1-十一炔}的相结构与相转变.高分子学报.
MLA	余振强,et al."聚{11-[(4'-正庚氧基-4-联苯基)羰基]氧-1-十一炔}的相结构与相转变".高分子学报 (2010).