Synthesis and Characterization of a Fluorotitanophosphate   (NH4)(0.16)K-1.84[Ti2F2(PO4)(2)(PO3OH)] with a Unique Lamella Framework

doi:10.1021/ic900504m

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	Synthesis and Characterization of a Fluorotitanophosphate (NH4)(0.16)K-1.84[Ti2F2(PO4)(2)(PO3OH)] with a Unique Lamella Framework
	Yang, Sihai ; Li, Guobao ; Liu, Wei ; Wang, Wei ; Yan, Zhimin ; Huang, Yining ; Liao, Fuhui ; Lin, Jianhua
刊名	inorganic chemistry
	2009
关键词	GAMMA-TITANIUM PHOSPHATE HYDROTHERMAL SYNTHESIS STRUCTURAL-CHARACTERIZATION INTERCALATION BEHAVIOR HETEROCYCLIC AMINES POWDER DIFFRACTION CRYSTAL-STRUCTURE NMR HYDROGENPHOSPHATE CSH2PO4
DOI	10.1021/ic900504m
英文摘要	(NH4)(0.16)K-1.84[Ti2F2(PO4)(2)(PO3OH)] (1) has been synthesized under hydrothermal conditions. The structure, the composition, and the thermal stability of 1 were determined by single-crystal X-ray diffraction; inductively coupled plasma-optical emission spectroscopy; IR spectroscopy; elemental analysis; thermogravimetric analysis-differential scanning calorimetry-mass spectrometry; and solid-state H-1, P-31, and F-19 NMR, and the phase purity of the bulk sample was checked by powder X-ray diffraction. Complex 1 is a fluorotitanophosphate having a unique lamella framework with both TiO5F octahedra and PO3OH tetrahedra on the surface of the layer, which leads to two different hydrogen bondings involving both P-OH and Ti-F groups.; Chemistry, Inorganic & Nuclear; SCI(E); PubMed; 1; ARTICLE; 12; 5449-5453; 48
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/312608]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Yang, Sihai,Li, Guobao,Liu, Wei,et al. Synthesis and Characterization of a Fluorotitanophosphate (NH4)(0.16)K-1.84[Ti2F2(PO4)(2)(PO3OH)] with a Unique Lamella Framework[J]. inorganic chemistry,2009.
APA	Yang, Sihai.,Li, Guobao.,Liu, Wei.,Wang, Wei.,Yan, Zhimin.,...&Lin, Jianhua.(2009).Synthesis and Characterization of a Fluorotitanophosphate (NH4)(0.16)K-1.84[Ti2F2(PO4)(2)(PO3OH)] with a Unique Lamella Framework.inorganic chemistry.
MLA	Yang, Sihai,et al."Synthesis and Characterization of a Fluorotitanophosphate (NH4)(0.16)K-1.84[Ti2F2(PO4)(2)(PO3OH)] with a Unique Lamella Framework".inorganic chemistry (2009).