Synthesis and crystal structure of a polymeric complex   [S4Cd17(SPh)(24)(CH3OCS2)(4/2)](n)center dot nCH(3)OH

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	Synthesis and crystal structure of a polymeric complex [S4Cd17(SPh)(24)(CH3OCS2)(4/2)](n)center dot nCH(3)OH
	Jin, XG ; Tang, KL ; Jia, SJ ; Tang, YQ
刊名	polyhedron
	1996
关键词	CU-S BONDS INSERTION REACTION CS2 CLUSTERS PRODUCT
DOI	10.1016/0277-5387(95)00544-7
英文摘要	The three dimensional polymeric complex [S4Cd17(SPh)(24)(CH3OCS2)(4/2)](n) . nCH(3)OH (1) has been synthesized from the reaction of [Cd-4(SPh)(6)(SPh)(4/2)](n) with CS2, DMF and MeOH, and structurally characterized by X-ray diffraction analysis. Its repeat unit is a 17-nuclear cadmium cluster which is linked to four surrounding aggregates through four CH3OSC2- ligands. The method of synthesis is also discussed. Copyright (C) 1996 Elsevier Science Ltd.; Chemistry, Inorganic & Nuclear; Crystallography; SCI(E); 23; ARTICLE; 15; 2617-2622; 15
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/258373]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Jin, XG,Tang, KL,Jia, SJ,et al. Synthesis and crystal structure of a polymeric complex [S4Cd17(SPh)(24)(CH3OCS2)(4/2)](n)center dot nCH(3)OH[J]. polyhedron,1996.
APA	Jin, XG,Tang, KL,Jia, SJ,&Tang, YQ.(1996).Synthesis and crystal structure of a polymeric complex [S4Cd17(SPh)(24)(CH3OCS2)(4/2)](n)center dot nCH(3)OH.polyhedron.
MLA	Jin, XG,et al."Synthesis and crystal structure of a polymeric complex [S4Cd17(SPh)(24)(CH3OCS2)(4/2)](n)center dot nCH(3)OH".polyhedron (1996).