Synthesis and crystal structure of a polymeric complex [S4Cd17(SPh)(24)(CH3OCS2)(4/2)](n)center dot nCH(3)OH | |
Jin, XG ; Tang, KL ; Jia, SJ ; Tang, YQ | |
刊名 | polyhedron
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1996 | |
关键词 | CU-S BONDS INSERTION REACTION CS2 CLUSTERS PRODUCT |
DOI | 10.1016/0277-5387(95)00544-7 |
英文摘要 | The three dimensional polymeric complex [S4Cd17(SPh)(24)(CH3OCS2)(4/2)](n) . nCH(3)OH (1) has been synthesized from the reaction of [Cd-4(SPh)(6)(SPh)(4/2)](n) with CS2, DMF and MeOH, and structurally characterized by X-ray diffraction analysis. Its repeat unit is a 17-nuclear cadmium cluster which is linked to four surrounding aggregates through four CH3OSC2- ligands. The method of synthesis is also discussed. Copyright (C) 1996 Elsevier Science Ltd.; Chemistry, Inorganic & Nuclear; Crystallography; SCI(E); 23; ARTICLE; 15; 2617-2622; 15 |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://ir.pku.edu.cn/handle/20.500.11897/258373] ![]() |
专题 | 化学与分子工程学院 |
推荐引用方式 GB/T 7714 | Jin, XG,Tang, KL,Jia, SJ,et al. Synthesis and crystal structure of a polymeric complex [S4Cd17(SPh)(24)(CH3OCS2)(4/2)](n)center dot nCH(3)OH[J]. polyhedron,1996. |
APA | Jin, XG,Tang, KL,Jia, SJ,&Tang, YQ.(1996).Synthesis and crystal structure of a polymeric complex [S4Cd17(SPh)(24)(CH3OCS2)(4/2)](n)center dot nCH(3)OH.polyhedron. |
MLA | Jin, XG,et al."Synthesis and crystal structure of a polymeric complex [S4Cd17(SPh)(24)(CH3OCS2)(4/2)](n)center dot nCH(3)OH".polyhedron (1996). |
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