CATALYTIC EFFECTS OF PEROXIDASE-LIKE METALLOPORPHYRINS ON THE   CHROMOGENIC REACTION OF 4-AMINOANTIPYRINE AND P-CHLOROPHENIC ACID WITH   HYDROGEN-PEROXIDE

doi:10.1007/BF00322769

CORC > 北京大学 > 化学与分子工程学院

	CATALYTIC EFFECTS OF PEROXIDASE-LIKE METALLOPORPHYRINS ON THE CHROMOGENIC REACTION OF 4-AMINOANTIPYRINE AND P-CHLOROPHENIC ACID WITH HYDROGEN-PEROXIDE
	WANG, F ; WU, YZ ; WU, XW ; SUN, SS ; CI, YX
刊名	fresenius journal of analytical chemistry
	1993
关键词	HOMOVANILLIC-ACID
DOI	10.1007/BF00322769
英文摘要	The catalytic efficiency of peroxidase-like metalloporphyrins has been studied for catalyzing the chromogenic reaction of 4-aminoantipyrine and p-chlorophenic acid with hydrogen peroxide. These metalloporphyrins include hemin and the complexes of Mn, Fe, Co, Ni, Cu, Zn, Pt, Rh and Pd with tetrakis(N-methylpyridinium)porphyrin (TMPyP), of Mn, Fe, Co, Ni, Cu, Zn, Ag and Sn with tetrakis(sulphophenyl)porphyrin (TPPS4), and of Fe with tetrakis(4-(N,N,N-trimethylaminophenyl)porphyrin (TAPP). It has been found that the complexes of Mn, Fe, Co, Cu, Ag, Pt, Pd and Rh catalyzed the formation of the chromogenic product, while those of Ni, Zn and Sn did not. Traces of hydrogen peroxide and, indirectly, glucose can be determined by means of the metalloporphyrins. The characteristics of peroxidase-like metalloporphyrins have been compared with those of horseradish peroxidase.; Chemistry, Analytical; SCI(E); 3; ARTICLE; 10-11; 1011-1013; 346
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/258349]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	WANG, F,WU, YZ,WU, XW,et al. CATALYTIC EFFECTS OF PEROXIDASE-LIKE METALLOPORPHYRINS ON THE CHROMOGENIC REACTION OF 4-AMINOANTIPYRINE AND P-CHLOROPHENIC ACID WITH HYDROGEN-PEROXIDE[J]. fresenius journal of analytical chemistry,1993.
APA	WANG, F,WU, YZ,WU, XW,SUN, SS,&CI, YX.(1993).CATALYTIC EFFECTS OF PEROXIDASE-LIKE METALLOPORPHYRINS ON THE CHROMOGENIC REACTION OF 4-AMINOANTIPYRINE AND P-CHLOROPHENIC ACID WITH HYDROGEN-PEROXIDE.fresenius journal of analytical chemistry.
MLA	WANG, F,et al."CATALYTIC EFFECTS OF PEROXIDASE-LIKE METALLOPORPHYRINS ON THE CHROMOGENIC REACTION OF 4-AMINOANTIPYRINE AND P-CHLOROPHENIC ACID WITH HYDROGEN-PEROXIDE".fresenius journal of analytical chemistry (1993).