Synthesis, photophysics, photochemistry, electrochemistry and structural   studies of luminescent rhenium(I) surfactant complexes; non-linear   optical properties in Langmuir-Blodgett films

doi:10.1039/a705015a

CORC > 北京大学 > 化学与分子工程学院

	Synthesis, photophysics, photochemistry, electrochemistry and structural studies of luminescent rhenium(I) surfactant complexes; non-linear optical properties in Langmuir-Blodgett films
	Yam, VWW ; Lau, VCY ; Wang, KZ ; Cheung, KK ; Huang, CH
刊名	材料化学杂志
	1998
关键词	INTRAMOLECULAR ELECTRON-TRANSFER ORGANIZED MONOLAYER ASSEMBLIES RAY CRYSTAL-STRUCTURE METALLIC CARBONYL-COMPLEXES CHARGE-TRANSFER EMISSION 2ND HARMONIC-GENERATION TRANSFER EXCITED-STATES ENERGY-TRANSFER CASCADE TERNARY COMPLEXES INVERTED REGION
DOI	10.1039/a705015a
英文摘要	A series of structurally related rhenium(I) tricarbonyl diimine surfactant-active complexes, [Re(CO)(3)(diimine){py(CH(2))(n)CH(3)}](+) and [Re(CO)(3)(diimine){pyCO(Chol)}](+) have been synthesized (n = 0, 1, 4, 12, 14, 16, 18; py = pyridyl, Chol = cholesteryl), and their photophysical, photochemical and electrochemical properties studied. A systematic study on the dependence of their photophysical properties in different environments has also been presented. In general, there is no apparent change in the photophysical behavior of these complexes as a function of the chain length of the surfactant type pyridyl ligands, the mechanism of which has been discussed. Langmuir-Blodgett films of the complexes have been prepared, and their pi-A isotherms, together with their electronic absorption and emission properties studied. The second harmonic generation (SHG) properties of the LB films have also been investigated. The X-ray crystal structure of a surfactant rhenium(I) complex, [Re(bpy)(CO)(3)(pyC(17)H(35))]ClO(4) has been determined.; Chemistry, Physical; Materials Science, Multidisciplinary; SCI(E); 14; ARTICLE; 1; 89-97; 8
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/257875]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Yam, VWW,Lau, VCY,Wang, KZ,et al. Synthesis, photophysics, photochemistry, electrochemistry and structural studies of luminescent rhenium(I) surfactant complexes; non-linear optical properties in Langmuir-Blodgett films[J]. 材料化学杂志,1998.
APA	Yam, VWW,Lau, VCY,Wang, KZ,Cheung, KK,&Huang, CH.(1998).Synthesis, photophysics, photochemistry, electrochemistry and structural studies of luminescent rhenium(I) surfactant complexes; non-linear optical properties in Langmuir-Blodgett films.材料化学杂志.
MLA	Yam, VWW,et al."Synthesis, photophysics, photochemistry, electrochemistry and structural studies of luminescent rhenium(I) surfactant complexes; non-linear optical properties in Langmuir-Blodgett films".材料化学杂志 (1998).