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Synthesis, crystal structure and magnetic property of Sm(2-x)Co(x)Ti(2-x)Nb(x)O7 (x=0, 0.2, 0.4)
Li, XL ; Song, YW ; Xiong, H ; Jia, YQ ; Matsushita, N ; Xuan, Y
刊名材料化学与材料物理学
2003
关键词pyrochlore compound crystal structure Van Vleck paramagnetism canted ferrimagnet semi-spin glass PYROCHLORE COMPOUNDS OXIDES
DOI10.1016/S0254-0584(01)00587-9
英文摘要SM2-xCoxTi2-xNbxO7 (X = 0, 0.2, 0.4) were synthesized by a wet chemical method. The compounds possess pyrochlore structure with cubic face-central cell. The lattice parameter (a) is 1.0234 nm for Sm2Ti2O7, 1.0231 nm for Sm1.8Co0.2Ti1.8Nb0.2O7 and 1.0225nm for Sm1.6Co0.4Ti1.6Nb0.4O7. Sm2Ti2O7 may possess the Van Vleck paramagnetism. The variation of the magnetic susceptibility Of Sm2-xCoxTi2-xNbxO7 (X = 0.2, 0.4) with temperature is similar to that of a ferrimagnet in the paramagnetic region. The satisfactory fitting to the experimental plot of the inverse susceptibility of Sm2-xCoxTi2-xNbxO7 (X = 0.2, 0.4) vs. temperature indicates that the compounds may be a canted ferrimagnet. (C) 2002 Elsevier Science B.V. All rights reserved.; http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000178843700002&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=8e1609b174ce4e31116a60747a720701 ; Materials Science, Multidisciplinary; SCI(E); EI; 0; ARTICLE; 3; 625-631; 77
语种英语
内容类型期刊论文
源URL[http://ir.pku.edu.cn/handle/20.500.11897/256202]  
专题化学与分子工程学院
推荐引用方式
GB/T 7714
Li, XL,Song, YW,Xiong, H,et al. Synthesis, crystal structure and magnetic property of Sm(2-x)Co(x)Ti(2-x)Nb(x)O7 (x=0, 0.2, 0.4)[J]. 材料化学与材料物理学,2003.
APA Li, XL,Song, YW,Xiong, H,Jia, YQ,Matsushita, N,&Xuan, Y.(2003).Synthesis, crystal structure and magnetic property of Sm(2-x)Co(x)Ti(2-x)Nb(x)O7 (x=0, 0.2, 0.4).材料化学与材料物理学.
MLA Li, XL,et al."Synthesis, crystal structure and magnetic property of Sm(2-x)Co(x)Ti(2-x)Nb(x)O7 (x=0, 0.2, 0.4)".材料化学与材料物理学 (2003).
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