[{(NiOH)(2)Mo10O36(PO4)Ti-2}(n)](5n-): a novel chainlike trimetal   heteropolyanion based on pseudo-keggin fragments

doi:10.1016/S0022-4596(02)00059-2

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	[{(NiOH)(2)Mo10O36(PO4)Ti-2}(n)](5n-): a novel chainlike trimetal heteropolyanion based on pseudo-keggin fragments
	Zhang, H ; Li, YG ; Duan, LY ; Lan, Y ; Wang, EB ; Hu, CW ; Yao, YG ; Chen, JT ; Gao, S
刊名	journal of solid state chemistry
	2003
关键词	pseudo-keggin structure trimetal heteropolyanion chainlike single crystal CRYSTAL-STRUCTURE HYDROTHERMAL SYNTHESIS MOLYBDENUM PHOSPHATE FRAMEWORK MATERIALS BUILDING-BLOCKS CLUSTERS CATALYSIS TUNNEL
DOI	10.1016/S0022-4596(02)00059-2
英文摘要	A new mixed Mo/Ni/Ti heteropoly compound [C5H5NH]5 [(NiOH)(2)Mo10O36(PO4)Ti-2] has been hydrothermally synthesized and structurally determined by the single-crystal X-ray diffraction. Black prismatic crystals crystallize in the monoclinic system, space group P2(1)/n, a = 11.2075(2), b = 37.8328(5) e = 13.0888(l),Angstrom, beta = 101.4580(10)degrees, M = 2276.13, V = 5439.19(13),Angstrom(3), Z = 4. Data were collected on a Siemens SMART CCD diffractometer at 293(2) K in the range of 1.68 < 0 < 25.09degrees using the omega-scan technique lambda = 0.71073 Angstrom R(F) = 0.0872 for 9621 reflections). The title compound contains a trimetal heteropolyanion polymer and "transtitanium"-bridging pseudo-Keggin fragments linked to a chain. (C) 2002 Elsevier Science (USA). All rights reserved.; Chemistry, Inorganic & Nuclear; Chemistry, Physical; SCI(E); EI; 4; ARTICLE; 2; 232-236; 170
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/256185]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Zhang, H,Li, YG,Duan, LY,et al. [{(NiOH)(2)Mo10O36(PO4)Ti-2}(n)](5n-): a novel chainlike trimetal heteropolyanion based on pseudo-keggin fragments[J]. journal of solid state chemistry,2003.
APA	Zhang, H.,Li, YG.,Duan, LY.,Lan, Y.,Wang, EB.,...&Gao, S.(2003).[{(NiOH)(2)Mo10O36(PO4)Ti-2}(n)](5n-): a novel chainlike trimetal heteropolyanion based on pseudo-keggin fragments.journal of solid state chemistry.
MLA	Zhang, H,et al."[{(NiOH)(2)Mo10O36(PO4)Ti-2}(n)](5n-): a novel chainlike trimetal heteropolyanion based on pseudo-keggin fragments".journal of solid state chemistry (2003).