Aliphatic acetylenic homocoupling catalyzed by a novel combination of   AgOTs-CuCl2-TMEDA and its application for the solid-phase synthesis of   bis-benzo[b]furan-linked 1,3-diynes

doi:10.1021/ol030009g

CORC > 北京大学 > 化学与分子工程学院

	Aliphatic acetylenic homocoupling catalyzed by a novel combination of AgOTs-CuCl2-TMEDA and its application for the solid-phase synthesis of bis-benzo[b]furan-linked 1,3-diynes
	Liao, Y ; Fathi, R ; Yang, Z
刊名	organic letters
	2003
关键词	PROTEIN DIMERIZERS SILYL LINKER MACROBEADS DISCOVERY SUPPORT DIYNES ROUTE
DOI	10.1021/ol030009g
英文摘要	A novel catalytic system of AgOTs-CuCl2-TMEDA is described for the homocoupling of aliphatic acetylenes on solid support. It is the first observation that Ag-l's activating triple bond could facilitate Cu-II-mediated oxidative acetylenic homocoupling. This study provides an efficient way to synthesize a diversified symmetrical bis-benzo[b]furan-linked 1,3-diyne library on solid support.; Chemistry, Organic; SCI(E); 51; ARTICLE; 6; 909-912; 5
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/256030]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Liao, Y,Fathi, R,Yang, Z. Aliphatic acetylenic homocoupling catalyzed by a novel combination of AgOTs-CuCl2-TMEDA and its application for the solid-phase synthesis of bis-benzo[b]furan-linked 1,3-diynes[J]. organic letters,2003.
APA	Liao, Y,Fathi, R,&Yang, Z.(2003).Aliphatic acetylenic homocoupling catalyzed by a novel combination of AgOTs-CuCl2-TMEDA and its application for the solid-phase synthesis of bis-benzo[b]furan-linked 1,3-diynes.organic letters.
MLA	Liao, Y,et al."Aliphatic acetylenic homocoupling catalyzed by a novel combination of AgOTs-CuCl2-TMEDA and its application for the solid-phase synthesis of bis-benzo[b]furan-linked 1,3-diynes".organic letters (2003).