Structure and photoelectrochemical properties of ruthenium(II)   polypyridyl complexes as sensitizers for nanocrystalline TiO2 electrodes

doi:10.1016/S0927-0248(03)00016-3

CORC > 北京大学 > 化学与分子工程学院

	Structure and photoelectrochemical properties of ruthenium(II) polypyridyl complexes as sensitizers for nanocrystalline TiO2 electrodes
	Yao, QH ; Huang, YY ; Song, LQ ; Zhang, BW ; Huang, CH ; Wang, ZS ; Li, FY ; Zhao, XS
刊名	solar energy materials and solar cells
	2003
关键词	photoelectric conversion polypyridyl complex sensitization nanocrystalline TiO2 SOLAR-CELLS CHARGE RECOMBINATION LIGHT DERIVATIVES SEPARATION INTERFACES CONVERSION TRANSPORT FILMS
DOI	10.1016/S0927-0248(03)00016-3
英文摘要	The relationship between the structures and photoelectrochemical properties of two dyes, cis-dithiocyanato-N,N'-bis(4,4'-dicarboxyl-2,2'-bipyridyl) Ru(II) and cis-dithiocyanato(4,4'-dicarboxyl-2,2'-bipyridyl)-(4,4'-di((N,N-methylphenylamino)methylene)-2,2'-bipyridyl) Ru(II), was examined and compared under the same conditions. Data show that the photophysical properties (including molar extinction coefficients - and excited-state lifetimes) and photoelectrochemical properties (including short-circuit photocurrent, open-circuit photovoltage, incident monochromatic photon to current conversion efficiency, overall energy conversion yield (eta) and transient photocurrent) were changed greatly only due to an acceptor replaced by a donor in one of polypyridyl of the Ru(II) complex, suggesting that the molecular design in energy conversion is very sensitive. (C) 2003 Elsevier Science B.V. All rights reserved.; Energy & Fuels; Materials Science, Multidisciplinary; Physics, Applied; SCI(E); EI; 9; LETTER; 3; 319-330; 77
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/255899]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Yao, QH,Huang, YY,Song, LQ,et al. Structure and photoelectrochemical properties of ruthenium(II) polypyridyl complexes as sensitizers for nanocrystalline TiO2 electrodes[J]. solar energy materials and solar cells,2003.
APA	Yao, QH.,Huang, YY.,Song, LQ.,Zhang, BW.,Huang, CH.,...&Zhao, XS.(2003).Structure and photoelectrochemical properties of ruthenium(II) polypyridyl complexes as sensitizers for nanocrystalline TiO2 electrodes.solar energy materials and solar cells.
MLA	Yao, QH,et al."Structure and photoelectrochemical properties of ruthenium(II) polypyridyl complexes as sensitizers for nanocrystalline TiO2 electrodes".solar energy materials and solar cells (2003).