Synthesis and crystal structure of a molybdenum complex of fullerene, [Mo(��2-C60)(CO)2(dpphen)(dbf) dbf = dibutyl fumarate) | |
Xie, Xiangjin ; Jin, Xianglin ; Tang, Kaluo | |
刊名 | transition metal chemistry |
2003 | |
DOI | 10.1023/A:1026061912636 |
英文摘要 | The molybdenum complex [Mo(??2-C60)(CO)2(dpphen)(dbf)] (1) [dpphen = 4,7-diphenyl-1,10-phenanthroline; dbf = dibutyl fumarate] has been prepared and structurally characterized by X-ray diffraction analysis. In the molecule of (1), the coordination geometry of the Mo atom is distorted octahedral with the phen (1,10-phenanthroline) group of dpphen and two CO groups in the equatorial plane. The Mo atom binds in an ??2-fashion to the C-C bonds of C60 and dbf. The two C-C bonds are almost mutually orthogonal.; SCI(E); EI; 0; 7; 741-744; 28 |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://ir.pku.edu.cn/handle/20.500.11897/255694] |
专题 | 化学与分子工程学院 |
推荐引用方式 GB/T 7714 | Xie, Xiangjin,Jin, Xianglin,Tang, Kaluo. Synthesis and crystal structure of a molybdenum complex of fullerene, [Mo(��2-C60)(CO)2(dpphen)(dbf) dbf = dibutyl fumarate)[J]. transition metal chemistry,2003. |
APA | Xie, Xiangjin,Jin, Xianglin,&Tang, Kaluo.(2003).Synthesis and crystal structure of a molybdenum complex of fullerene, [Mo(��2-C60)(CO)2(dpphen)(dbf) dbf = dibutyl fumarate).transition metal chemistry. |
MLA | Xie, Xiangjin,et al."Synthesis and crystal structure of a molybdenum complex of fullerene, [Mo(��2-C60)(CO)2(dpphen)(dbf) dbf = dibutyl fumarate)".transition metal chemistry (2003). |
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