Crystal structure and magnetic behavior of a three-dimensional   cyano-bridged assembly [CuL1](2)[Cr(CN)(6)]ClO4 center dot 0.5H(2)O   (L-1=3,10-dipropyl-1,3,5,8,10,12-hexaazacyclotetradecane)

doi:10.1039/b401557f

CORC > 北京大学 > 化学与分子工程学院

	Crystal structure and magnetic behavior of a three-dimensional cyano-bridged assembly [CuL1](2)[Cr(CN)(6)]ClO4 center dot 0.5H(2)O (L-1=3,10-dipropyl-1,3,5,8,10,12-hexaazacyclotetradecane)
	Shen, XP ; Gao, S ; Yin, G ; Yu, KB ; Xu, Z
刊名	new journal of chemistry
	2004
关键词	MOLECULAR-BASED MAGNETS HIGH-SPIN MOLECULES BUILDING-BLOCKS BIMETALLIC ASSEMBLIES METAMAGNETIC PROPERTIES COPPER(II) COMPLEXES FERRICYANIDE CLUSTER ETHYLENEDIAMINE FERROMAGNET
DOI	10.1039/b401557f
英文摘要	Reaction of K-3[Cr(CN)(6)] with [CuL1](ClO4)(2) (L-1=3,10-dipropyl-1,3,5,8,10,12-hexaazacyclotetradecane) leads to a novel three-dimensional (3-D) cyano-bridged bimetallic assembly [CuL1](2)[Cr(CN)(6)]ClO4.0.5H(2)O (1), in which each hexacyanochromate(III) ion connects four copper(II) ions using four co-planar CN- groups, which coordinate axially to the copper ion in a trans fashion forming trans-CuL1(Nequivalent toC)(2) moieties. Magnetic studies reveal that the complex displays a ferromagnetic interaction between the Cu(II) (S=1/2) and Cr(III) (S=3/2) ions through cyano bridges.; http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000223221800014&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=8e1609b174ce4e31116a60747a720701 ; Chemistry, Multidisciplinary; SCI(E); 30; ARTICLE; 8; 996-999; 28
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/255620]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Shen, XP,Gao, S,Yin, G,et al. Crystal structure and magnetic behavior of a three-dimensional cyano-bridged assembly [CuL1](2)[Cr(CN)(6)]ClO4 center dot 0.5H(2)O (L-1=3,10-dipropyl-1,3,5,8,10,12-hexaazacyclotetradecane)[J]. new journal of chemistry,2004.
APA	Shen, XP,Gao, S,Yin, G,Yu, KB,&Xu, Z.(2004).Crystal structure and magnetic behavior of a three-dimensional cyano-bridged assembly [CuL1](2)[Cr(CN)(6)]ClO4 center dot 0.5H(2)O (L-1=3,10-dipropyl-1,3,5,8,10,12-hexaazacyclotetradecane).new journal of chemistry.
MLA	Shen, XP,et al."Crystal structure and magnetic behavior of a three-dimensional cyano-bridged assembly [CuL1](2)[Cr(CN)(6)]ClO4 center dot 0.5H(2)O (L-1=3,10-dipropyl-1,3,5,8,10,12-hexaazacyclotetradecane)".new journal of chemistry (2004).