Structure and magnetic properties of a novel copper diphosphonate with   pillared layered structure: Cu-2(H2O)(2){O3PCH2N(C2H4)(2)NCH2PO3}

doi:10.1016/j.jssc.2003.11.010

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	Structure and magnetic properties of a novel copper diphosphonate with pillared layered structure: Cu-2(H2O)(2){O3PCH2N(C2H4)(2)NCH2PO3}
	Wang, Y ; Bao, SS ; Xu, W ; Chen, JS ; Gao, S ; Zheng, LM
刊名	journal of solid state chemistry
	2004
关键词	copper diphosphonate N, N &apos ferromagnetic coupling CRYSTAL-STRUCTURES WEAK FERROMAGNET DOT H2O PHOSPHONATE CATALYSTS BEHAVIOR PHASES -piperazinebis(methylenephosphonate)
DOI	10.1016/j.jssc.2003.11.010
英文摘要	Compound CU2(H2O)(2){O3PCH2N(C2H4)(2)NCH2PO3} (1) has a pillared layered structure in which the organic groups of N, N'-piperazinebis(methylenephosphonate) are sandwiched between the inorganic layers. Compared with other copper phosphonates with layered or pillared layered structures, the inorganic layer in 1 is unique in that each {CPO3} tetrahedron is corner-shared with three {CuO4N} square pyramids through three oxygen donors. Ferromagnetic interactions are mediated between the metal centers. Crystal data: Pbca, a = 10.0830(16) Angstrom, b = 9.4517(15) Angstrom, c = 13.218(2) Angstrom, V - 1259.7(3) Angstrom(3), Z = 4. (C) 2003 Elsevier Inc. All rights reserved.; Chemistry, Inorganic & Nuclear; Chemistry, Physical; SCI(E); EI; 0; ARTICLE; 4-5; 1297-1301; 177
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/255378]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Wang, Y,Bao, SS,Xu, W,et al. Structure and magnetic properties of a novel copper diphosphonate with pillared layered structure: Cu-2(H2O)(2){O3PCH2N(C2H4)(2)NCH2PO3}[J]. journal of solid state chemistry,2004.
APA	Wang, Y,Bao, SS,Xu, W,Chen, JS,Gao, S,&Zheng, LM.(2004).Structure and magnetic properties of a novel copper diphosphonate with pillared layered structure: Cu-2(H2O)(2){O3PCH2N(C2H4)(2)NCH2PO3}.journal of solid state chemistry.
MLA	Wang, Y,et al."Structure and magnetic properties of a novel copper diphosphonate with pillared layered structure: Cu-2(H2O)(2){O3PCH2N(C2H4)(2)NCH2PO3}".journal of solid state chemistry (2004).