Synthesis and chemical properties of conjugated polyacetylenes having   pendant fullerene and/or porphyrin units

doi:10.1021/ma0490045

CORC > 北京大学 > 化学与分子工程学院

	Synthesis and chemical properties of conjugated polyacetylenes having pendant fullerene and/or porphyrin units
	Lu, FS ; Xiao, SQ ; Li, YL ; Liu, HB ; Li, HM ; Zhuang, JP ; Liu, Y ; Wang, N ; He, XR ; Li, XF ; Gan, LB ; Zhu, DB
刊名	macromolecules
	2004
关键词	PHOTOINDUCED ELECTRON-TRANSFER SELF-ASSEMBLED MONOLAYERS CHARGE SEPARATION PHOTOCURRENT GENERATION STEREOREGULAR POLYMERIZATION MULTIPORPHYRIN ARRAYS NITROXIDE RADICALS COMPLEX ENERGY DYADS
DOI	10.1021/ma0490045
英文摘要	Conjugated polyacetylenes having pendant fullerene and/or porphyrin groups were prepared by copolymerization in the presence of [Rh(nbd)Cl](2)-NEt3 in CHCl3. The photochemical and electrochemical properties of the polymers were studied by UV-vis spectroscopy and voltammetry. The photoinduced charge-transfer properties of the monolayer films were also measured by a three-electrode cell technique. More importantly, poly(1a(0.2)-co-5(0.8)) shows a high capacity to form a photoinduced charge-separated state and to produce steady and prompt photocurrent at the irradiation of 21.2 mW cm(-2) white light. We estimate an aerobic IPCE value of 0.15% for a true monolayer coverage of poly(1a(0.2)-co-5(0.8)) at its peak absorption around 440 nm (the maximum of the Soret band).; http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000224197500005&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=8e1609b174ce4e31116a60747a720701 ; Polymer Science; SCI(E); EI; 37; ARTICLE; 20; 7444-7450; 37
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/254818]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Lu, FS,Xiao, SQ,Li, YL,et al. Synthesis and chemical properties of conjugated polyacetylenes having pendant fullerene and/or porphyrin units[J]. macromolecules,2004.
APA	Lu, FS.,Xiao, SQ.,Li, YL.,Liu, HB.,Li, HM.,...&Zhu, DB.(2004).Synthesis and chemical properties of conjugated polyacetylenes having pendant fullerene and/or porphyrin units.macromolecules.
MLA	Lu, FS,et al."Synthesis and chemical properties of conjugated polyacetylenes having pendant fullerene and/or porphyrin units".macromolecules (2004).