Chiral imides as potential chiroptical switches: synthesis and optical properties | |
Todd, EK ; Wang, S ; Wan, XH ; Wang, ZY | |
刊名 | 四面体通讯
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2005 | |
关键词 | chiral chiroptical perylene imides naphthalene imides electrochromic fluorescence MOLECULAR SWITCHES CIRCULAR-DICHROISM PERYLENE DYES ELECTROCHEMISTRY FLUORESCENCE DERIVATIVES DIIMIDES SPECTRA DEVICES |
DOI | 10.1016/j.tetlet.2004.11.147 |
英文摘要 | A series of chiral aromatic imides and diimides were synthesized and their electrochemical, absorption, fluorescent, and chiroptical properties were examined for their potential application as molecular chiroptical switches. These compounds exhibit strong UV-vis absorptions, and can be electrochemically reduced to radical anions that absorb in the near infrared (NIR) region. Further reduction to the dianionic states results in new absorptions in the visible region. The changes in circular dichroism upon redox switching were apparent in the UV-vis region but were absent in the NIR region. (C) 2004 Elsevier Ltd. All rights reserved.; Chemistry, Organic; SCI(E); 21; ARTICLE; 4; 587-590; 46 |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://ir.pku.edu.cn/handle/20.500.11897/254501] ![]() |
专题 | 化学与分子工程学院 |
推荐引用方式 GB/T 7714 | Todd, EK,Wang, S,Wan, XH,et al. Chiral imides as potential chiroptical switches: synthesis and optical properties[J]. 四面体通讯,2005. |
APA | Todd, EK,Wang, S,Wan, XH,&Wang, ZY.(2005).Chiral imides as potential chiroptical switches: synthesis and optical properties.四面体通讯. |
MLA | Todd, EK,et al."Chiral imides as potential chiroptical switches: synthesis and optical properties".四面体通讯 (2005). |
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