Heterometallic (MRu2III)-Ru-II compounds constructed from   trans-[Ru(Salen)(CN)(2)](-) and trans-[Ru(AcaC)(2)(CN)(2)](-),   synthesis, structures, magnetic properties, and density functional   theoretical study

doi:10.1021/ic0506456

CORC > 北京大学 > 化学与分子工程学院

	Heterometallic (MRu2III)-Ru-II compounds constructed from trans-[Ru(Salen)(CN)(2)](-) and trans-[Ru(AcaC)(2)(CN)(2)](-), synthesis, structures, magnetic properties, and density functional theoretical study
	Yeung, WF ; Lau, PH ; Lau, TC ; Wei, HY ; Sun, HL ; Gao, S ; Chen, ZD ; Wong, WT
刊名	inorganic chemistry
	2005
关键词	BRIDGED BIMETALLIC COMPOUND SINGLE-MOLECULE MAGNETS CRYSTAL-STRUCTURE ORDERING TEMPERATURE COORDINATION POLYMERS SPIN REORIENTATION BUILDING-BLOCKS PRUSSIAN-BLUE MIXED-VALENCE DEGREES-C
DOI	10.1021/ic0506456
英文摘要	The synthesis, structures, and magnetic properties of four cyano-bridged (MRu2lll)-Ru-ll compounds prepared from the paramagnetic Ru-lll building blocks, trans-[Ru(salen)(CN)(2)](-1) [H(2)salen = N,N'-(-ethylenebis(salicylideneimine)] and trans-[Ru(acac)(2)(CN)(2)](-) (Hacac = acetylacetone), are described. Compound 2, {Mn(CH3OH)(4)[Ru(salen)(CN)(2)](2)}center dot 6CH(3)OH-2H(2)O, is a trinuclear complex that exhibits antiferromagnetic coupling between Mn-ll and Ru-lll centers. Compound 3, {Mn(H2O)(2)[Ru(salen)(CN)(2)](2)(H2O2)-H-.}(n), has a 2-D sheetlike structure that exhibits antiferromagnetic coupling between Mn and Ru, leading to ferrimagnetic-like behavior. Compound 4, {Ni(cyclam)[Ru(acaC)(2)(CN)(2)](2)}center dot 2CH(3)OH center dot 2H2O (cyclam = 1,4,8,11 -tetraazacyclotetradecane), is a trinuclear complex that exhibits ferromagnetic coupling. Compound 5, {Co[Ru(acac)(2)(CN)(2)](2)}(n), has a 3-D diamond-like interpenetrating network that exhibits ferromagnetic ordering below 4.6 K. The density functional theory (DFT) method was used to calculate the molecular magnetic orbitals and the magnetic exchange interaction between Ru-lll and M-ll (Mn-ll, Ni-ll) ions.; http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000231860900018&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=8e1609b174ce4e31116a60747a720701 ; Chemistry, Inorganic & Nuclear; SCI(E); 59; ARTICLE; 19; 6579-6590; 44
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/254006]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Yeung, WF,Lau, PH,Lau, TC,et al. Heterometallic (MRu2III)-Ru-II compounds constructed from trans-[Ru(Salen)(CN)(2)](-) and trans-[Ru(AcaC)(2)(CN)(2)](-), synthesis, structures, magnetic properties, and density functional theoretical study[J]. inorganic chemistry,2005.
APA	Yeung, WF.,Lau, PH.,Lau, TC.,Wei, HY.,Sun, HL.,...&Wong, WT.(2005).Heterometallic (MRu2III)-Ru-II compounds constructed from trans-[Ru(Salen)(CN)(2)](-) and trans-[Ru(AcaC)(2)(CN)(2)](-), synthesis, structures, magnetic properties, and density functional theoretical study.inorganic chemistry.
MLA	Yeung, WF,et al."Heterometallic (MRu2III)-Ru-II compounds constructed from trans-[Ru(Salen)(CN)(2)](-) and trans-[Ru(AcaC)(2)(CN)(2)](-), synthesis, structures, magnetic properties, and density functional theoretical study".inorganic chemistry (2005).