Studies of Langmuir-Blodgett films of an ion pair metal complex   containing Eu(III)-Ru(II) dual chromophores

doi:10.1021/jp054525v

CORC > 北京大学 > 化学与分子工程学院

	Studies of Langmuir-Blodgett films of an ion pair metal complex containing Eu(III)-Ru(II) dual chromophores
	Gao, LH ; Wang, KZ ; Cai, L ; Zhang, HX ; Jin, LP ; Huang, CH ; Gao, HJ
刊名	journal of physical chemistry b
	2006
关键词	AMPHIPHILIC RU COMPLEXES AIR-WATER-INTERFACE RUTHENIUM COMPLEX 2ND-HARMONIC GENERATION STRUCTURAL-CHARACTERIZATION ELECTROCHEMICAL PROPERTIES EUROPIUM(III) COMPLEXES ENERGY-TRANSFER SOLID-STATE MONOLAYERS
DOI	10.1021/jp054525v
英文摘要	A surfactant ion-pair complex, [Ru(bPY)(2)L] [Eu(NTA)(4)](2) (in which L = 1-docosyl-2-(2-pyfidyl)benzimidazole, bpy = 2,2 '-bipyridine, and NTA = 4,4,4-trifluoro-1-(2-naphthyl)-1,3-butanedionato) has been synthesized. The surface pressure-area isotherm measurements show that the complex forms a stable Langmuir film at the air-water interface without adding any electrolytes into the subphase. The monolayers formed at the surface pressures of 5 mN m(-1) and 20 mN m(-1), have been successfully transferred onto glass and quartz substrates with the transfer ratios close to unity. The Lanumuir-Blodgett films were studied by UV-visible, infrared, and emission spectroscopies, atomic force microscopy, and cyclic voltammetry. The optical, redox, and morphology properties of the LB films were found to be significantly affected by the target surface pressures used for the film depositions.; Chemistry, Physical; SCI(E); EI; 0; ARTICLE; 14; 7402-7408; 110
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/252471]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Gao, LH,Wang, KZ,Cai, L,et al. Studies of Langmuir-Blodgett films of an ion pair metal complex containing Eu(III)-Ru(II) dual chromophores[J]. journal of physical chemistry b,2006.
APA	Gao, LH.,Wang, KZ.,Cai, L.,Zhang, HX.,Jin, LP.,...&Gao, HJ.(2006).Studies of Langmuir-Blodgett films of an ion pair metal complex containing Eu(III)-Ru(II) dual chromophores.journal of physical chemistry b.
MLA	Gao, LH,et al."Studies of Langmuir-Blodgett films of an ion pair metal complex containing Eu(III)-Ru(II) dual chromophores".journal of physical chemistry b (2006).