稀土纳米发光材料的燃烧法制备及光谱性质

doi:10.3321/j.issn:1000-0593.2006.02.010

CORC > 北京大学 > 化学与分子工程学院

	稀土纳米发光材料的燃烧法制备及光谱性质; Spectrum and Synthesis of Rare Earth Activated Nanoparticle
	常建军 ; 黄世华 ; 彭洪尚 ; 孟春霞 ; 由芳田 ; 吕少哲 ; 孙聆东
刊名	光谱学与光谱分析
	2006
关键词	燃烧法稀土纳米材料 La2O3 Eu3+ 激光选择激发 combustion rare earth nanoparticle La2O3 : Eu3+ laser selective excitation
DOI	10.3321/j.issn:1000-0593.2006.02.010
英文摘要	用燃烧法制备了不同粒径的La2O3:Eu3+纳米微粒,研究了影响La2O3:Eu3+纳米微粒大小的实验条件,发现粒径大小随甘氨酸(Gly)与稀土离子比例的增大而减小.制备的纳米微粒由谢乐公式计算的粒径尺寸为12～28 nm.测量了样品的高分辨光谱.运用激光选择激发,研究了光谱在不同发光中心上的变化,表面态对于这些变化起着主要作用.; La2O3: Eu3+ nanoparticles were prepared by Gly assistant combustion synthesis with the sizes from 12-28 nm, and a characterization of XRD was done. Spectral properties of the nanoparticles were compared with the bulk. High resolution spectra were measured. Site selective excitation was employed to probe the local environments of Eu3+ ions in La2O3 nanoparticles. The luminescent centers on the surface and the center of the nanoparticles were excited respectively. The spectra were related to surface information. The luminescence from C-3v site and the site with lower symmetry on the surface was distinguished.; 中国科学院资助项目; http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000235638800010&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=8e1609b174ce4e31116a60747a720701 ; SCI(E); 中文核心期刊要目总览(PKU); 中国科技核心期刊(ISTIC); 中国科学引文数据库(CSCD); 7; 2; 231-234; 26
语种	中文
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/252360]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	常建军,黄世华,彭洪尚,等. 稀土纳米发光材料的燃烧法制备及光谱性质, Spectrum and Synthesis of Rare Earth Activated Nanoparticle[J]. 光谱学与光谱分析,2006.
APA	常建军.,黄世华.,彭洪尚.,孟春霞.,由芳田.,...&孙聆东.(2006).稀土纳米发光材料的燃烧法制备及光谱性质.光谱学与光谱分析.
MLA	常建军,et al."稀土纳米发光材料的燃烧法制备及光谱性质".光谱学与光谱分析 (2006).