Copper(II) and cobalt(II) coordination polymers with azido ions and 1,3-bis(4 '-pyridyl)propane | |
Gao, EQ ; Xu, YX ; Cheng, AL ; He, MY ; Yan, CH | |
刊名 | inorganic chemistry communications |
2006 | |
关键词 | coordination polymers azide magnetic properties crystal structures supramolecular isomerism MAGNETIC-PROPERTIES CRYSTAL-STRUCTURE BEHAVIOR COMPLEXES CHAINS DINUCLEAR ISOMERISM NETWORK BRIDGES SYSTEM |
DOI | 10.1016/j.inoche.2005.11.004 |
英文摘要 | A copper(II) complex [Cu(mu-1,3-N-3)(N-3)(bpp)](n) (1) (bpp = 1,3-bis(4'-pyridyl)propane) has been shown to exhibit a two-dimensional network formed by the bpp ligands interlinking copper(II)-azido chains, in which the single azido bridge assumes an asymmetric mu-1,3 mode and mediates weak ferromagnetic coupling. On the other hand, the reaction of cobalt(II), azido and bpp yielded two supramolecular isomers of [Co(N-3)(2)(bpp)(2)](n) (2 and 3) in which the azido ions serve as terminal ligands and the metal ions are linked by the bpp ligands in different conformations. (c) 2005 Elsevier B.V. All rights reserved.; Chemistry, Inorganic & Nuclear; SCI(E); 0; ARTICLE; 2; 212-215; 9 |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://ir.pku.edu.cn/handle/20.500.11897/252336] |
专题 | 化学与分子工程学院 |
推荐引用方式 GB/T 7714 | Gao, EQ,Xu, YX,Cheng, AL,et al. Copper(II) and cobalt(II) coordination polymers with azido ions and 1,3-bis(4 '-pyridyl)propane[J]. inorganic chemistry communications,2006. |
APA | Gao, EQ,Xu, YX,Cheng, AL,He, MY,&Yan, CH.(2006).Copper(II) and cobalt(II) coordination polymers with azido ions and 1,3-bis(4 '-pyridyl)propane.inorganic chemistry communications. |
MLA | Gao, EQ,et al."Copper(II) and cobalt(II) coordination polymers with azido ions and 1,3-bis(4 '-pyridyl)propane".inorganic chemistry communications (2006). |
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