Synthesis and structure of [C2H10N2][B5O8(OH)]: A nonmetal pentaborate   with nonlinear optical properties

doi:10.1021/cg0606794

CORC > 北京大学 > 化学与分子工程学院

	Synthesis and structure of [C2H10N2][B5O8(OH)]: A nonmetal pentaborate with nonlinear optical properties
	Yang, Sihai ; Li, Guobao ; Tian, Shujian ; Liao, Fuhui ; Lin, Jianhua
刊名	crystal growth design
	2007
关键词	BISMUTH BORATE BIB3O6 CRYSTAL-STRUCTURES 1ST EXAMPLES CALCIUM
DOI	10.1021/cg0606794
英文摘要	A nonmetal pentaborate [C2H10N2][B5O8(OH)] (I) was synthesized by a solvothermal method at 150 degrees C and characterized by elemental analysis, IR, thermogravimetric analysis, and X-ray diffraction. The structure of I was determined by a single-crystal technique. It crystallizes in the monoclinic system with space group Cc, a = 6.7085 (13) angstrom, b = 11.437(2) angstrom, c = 12.530(3) angstrom, and beta = 95.41(3)degrees. Powder second-harmonic generation (SHG) efficiency measurements with Nd:YAG laser (1064 nm) radiation show that [C2H10N2][B5O8(OH)] has a SHG efficiency approximately 1.2 times of that of potassium dihydrogen phosphate (KDP).; Chemistry, Multidisciplinary; Crystallography; Materials Science, Multidisciplinary; SCI(E); 33; ARTICLE; 7; 1246-1250; 7
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/250094]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Yang, Sihai,Li, Guobao,Tian, Shujian,et al. Synthesis and structure of [C2H10N2][B5O8(OH)]: A nonmetal pentaborate with nonlinear optical properties[J]. crystal growth design,2007.
APA	Yang, Sihai,Li, Guobao,Tian, Shujian,Liao, Fuhui,&Lin, Jianhua.(2007).Synthesis and structure of [C2H10N2][B5O8(OH)]: A nonmetal pentaborate with nonlinear optical properties.crystal growth design.
MLA	Yang, Sihai,et al."Synthesis and structure of [C2H10N2][B5O8(OH)]: A nonmetal pentaborate with nonlinear optical properties".crystal growth design (2007).