An unusual eight-connected self-penetrating ilc net constructed by   dinuclear lanthanide building units

doi:10.1039/b715058j

CORC > 北京大学 > 化学与分子工程学院

	An unusual eight-connected self-penetrating ilc net constructed by dinuclear lanthanide building units
	Cheng, Jian-Wen ; Zheng, Shou-Tian ; Liu, Wei ; Yang, Guo-Yu
刊名	crystengcomm
	2008
关键词	METAL-ORGANIC FRAMEWORKS COORDINATION POLYMER ISONICOTINATE LIGANDS CRYSTAL-STRUCTURE LAYERED NETWORKS CLUSTERS DESIGN CHEMISTRY TOPOLOGY SOLIDS
DOI	10.1039/b715058j
英文摘要	Hydrothermal reactions of Ln(2)(C(2)O(4))(3)center dot 9 H(2)O and CuCl(2)center dot 2 H(2)O with pyridine-2,3-dicarboxylic acid (H(2)pdc) in water in the presence of acetic acid lead to two novel three-dimensional lanthanide(III)-copper(I) heterometallic compounds: LnCu(na)(2)(C(2)O(4))center dot 1.5 H(2)O (L(n) = La 1, Ce 2; na = nicotinic acid). Both compounds are isostructural and contain two distinct units of 2D Ln-organic layers and nonlinear [Cu(na)(2)](-), the nonlinear [Cu(na)(2)]-act as pillars and further link the Ln-organic layers, resulting in two heterometallic metal-organic frameworks (MOFs) with two distinct types of channels along the a and c axes. Further structural analysis reveals that 1 is a scarcely reported eight-connected self-penetrating ilc net with dinuclear {Ln(2)} subunits as secondary building units. Furthermore, the IR, TGA, PXRD properties were also studied.; Chemistry, Multidisciplinary; Crystallography; SCI(E); 38; ARTICLE; 6; 765-769; 10
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/249341]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Cheng, Jian-Wen,Zheng, Shou-Tian,Liu, Wei,et al. An unusual eight-connected self-penetrating ilc net constructed by dinuclear lanthanide building units[J]. crystengcomm,2008.
APA	Cheng, Jian-Wen,Zheng, Shou-Tian,Liu, Wei,&Yang, Guo-Yu.(2008).An unusual eight-connected self-penetrating ilc net constructed by dinuclear lanthanide building units.crystengcomm.
MLA	Cheng, Jian-Wen,et al."An unusual eight-connected self-penetrating ilc net constructed by dinuclear lanthanide building units".crystengcomm (2008).