Crystal structure and magnetic property of a metal-organic framework   (MOF) containing double-stranded chain with metallomacrocycles and   dinuclear Mn(II) subunits

doi:10.1016/j.molstruc.2008.04.008

CORC > 北京大学 > 化学与分子工程学院

	Crystal structure and magnetic property of a metal-organic framework (MOF) containing double-stranded chain with metallomacrocycles and dinuclear Mn(II) subunits
	Qi, Chuanmin ; Zhang, Die ; Gao, Song ; Ma, Hui ; He, Yong ; Ma, Shulan ; Chen, Yufeng ; Yang, Xiaojing
刊名	分子结构杂志
	2008
关键词	Manganese(II) complex Benzimidazole carboxylic acid Double-stranded coordinating chain Metallomacrocycle Crystal structure Magnetic property X-RAY STRUCTURE NONPEPTIDE ANGIOTENSIN MANGANESE(II) COMPLEX CARBOXYLATE COMPLEXES RECEPTOR ANTAGONISTS CATALYTIC-PROPERTIES HYDROGEN STORAGE ANIONIC GUESTS LIGANDS DESIGN
DOI	10.1016/j.molstruc.2008.04.008
英文摘要	One new metal-organic framework (MOF)([Mn(2)L(2)(CH(3)OH)(2.5)H(2)O]center dot 2.5CH(3)OH center dot 5.5H(2)O)(n) 1 was prepared by assembling from the newly synthesized semirigid benzimidazole carboxylate ligand 2,6-bis(6-carboxy-4-methyl-2-propyl-benzimidazol-1 -ylmethyl)benzene (H(2)L) with Mn(II) ion. It contained novel 1 D double-stranded coordinating chain with metallomacrocycle and dinuclear Mn(II) subunit bridged by carboxylate ions. Variable temperature Susceptibility measurements (2-300 K) revealed an antiferromagnetic coupling interaction (J = -0.97 cm(-1)). The crystal structure and the magnetic behavior of 1 were discussed in detail. (C) 2008 Published by Elsevier B.V.; Chemistry, Physical; SCI(E); EI; 7; ARTICLE; 1-3; 357-363; 891
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/247903]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Qi, Chuanmin,Zhang, Die,Gao, Song,et al. Crystal structure and magnetic property of a metal-organic framework (MOF) containing double-stranded chain with metallomacrocycles and dinuclear Mn(II) subunits[J]. 分子结构杂志,2008.
APA	Qi, Chuanmin.,Zhang, Die.,Gao, Song.,Ma, Hui.,He, Yong.,...&Yang, Xiaojing.(2008).Crystal structure and magnetic property of a metal-organic framework (MOF) containing double-stranded chain with metallomacrocycles and dinuclear Mn(II) subunits.分子结构杂志.
MLA	Qi, Chuanmin,et al."Crystal structure and magnetic property of a metal-organic framework (MOF) containing double-stranded chain with metallomacrocycles and dinuclear Mn(II) subunits".分子结构杂志 (2008).