Synthesis of functionalized siloles from Si-tethered diynes

doi:10.1016/j.tetlet.2009.01.152

CORC > 北京大学 > 化学与分子工程学院

	Synthesis of functionalized siloles from Si-tethered diynes
	Luo, Qian ; Gu, Li ; Wang, Chao ; Liu, Junhui ; Zhang, Wenxiong ; Xi, Zhenfeng
刊名	四面体通讯
	2009
关键词	Silole Phenyl-bridged bis-silole 1,4-Dilithio-1,3-butadiene 1,4-Diiodo-1,3-butadiene Si-tethered diynes Zirconacyclopetadiene Cleavage of Si-C bond INTRAMOLECULAR REDUCTIVE CYCLIZATION PI-CONJUGATED OLIGOMERS C-C BOND TITANOCENE-BIS(TRIMETHYLSILYL)ETHYNE COMPLEXES ZIRCONACYCLOBUTENE-SILACYCLOBUTENE CYCLOPENTADIENE DERIVATIVES ELECTROLUMINESCENT DEVICES OPTOELECTRONIC PROPERTIES SKELETAL REARRANGEMENT OPTICAL-PROPERTIES
DOI	10.1016/j.tetlet.2009.01.152
英文摘要	A new synthetic itinerary to silole from Si-tethered diynes is reported. In this protocol, the Si-tethered diyne manifests definitely the reactivity of monoyne to form the lithio silole via zirconacyclopetadiene, 1,4-diiodo-1,3-butadiene, and the corresponding dilithiodiene successively. Lithio siloles thus obtained above could be easily functionalized to give various types of silole derivatives. Complex structure like bridged bis-silole compounds could also be constructed by this process. (C) 2009 Elsevier Ltd. All rights reserved.; http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000267070700022&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=8e1609b174ce4e31116a60747a720701 ; Chemistry, Organic; SCI(E); 12; ARTICLE; 26; 3213-3215; 50
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/247122]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Luo, Qian,Gu, Li,Wang, Chao,et al. Synthesis of functionalized siloles from Si-tethered diynes[J]. 四面体通讯,2009.
APA	Luo, Qian,Gu, Li,Wang, Chao,Liu, Junhui,Zhang, Wenxiong,&Xi, Zhenfeng.(2009).Synthesis of functionalized siloles from Si-tethered diynes.四面体通讯.
MLA	Luo, Qian,et al."Synthesis of functionalized siloles from Si-tethered diynes".四面体通讯 (2009).