Electrochemical synthesis of a ferrocenecarboxylic acid-C-60 composite   and its electrocatalysis to hydrogen peroxide

doi:10.1016/j.elecom.2009.10.043

CORC > 北京大学 > 化学与分子工程学院

	Electrochemical synthesis of a ferrocenecarboxylic acid-C-60 composite and its electrocatalysis to hydrogen peroxide
	Miao, Xiaopei ; Liu, Lu ; Wang, Shukuan ; Lin, Hong ; Sun, Baoyun ; Hu, Jingbo ; Li, Meixian
刊名	电化学通讯
	2010
关键词	C-60 Electrochemistry Ferrocenecarboxylic acid Electrocatalysis Hydrogen peroxide PHOTOINDUCED ELECTRON-TRANSFER CYTOCHROME-C FULLERENE C-60 POLYMER TRIADS DYADS FILM
DOI	10.1016/j.elecom.2009.10.043
英文摘要	A new ferrocenecarboxylic acid-C-60 composite (Fc-C-60) has been synthesized by controlled potential electrolysis. A composite modified glassy carbon electrode has been prepared based on its good electrochemical activity. The modified electrode in 0.1 M NaClO4 solution shows a reversible oxidation wave at E-1/2 = 0.32 V (vs. SCE) attributed to the oxidation of the ferrocene entity and a quasi-reversible reduction wave of C-60 entity at E-1/2 = -0.54 V (vs. SCE). Electrocatalytic studies show that Fc-C-60 at the modified electrode can mediate the reduction of hydrogen peroxide (H2O2), and a broad linear range from 1.2 mu M to 21.9 mM for H2O2 were obtained with a determination limit of 2.5 x 10(-7) M by amperometry. (C) 2009 Elsevier B.V. All rights reserved.; Electrochemistry; SCI(E); EI; 4; ARTICLE; 1; 90-93; 12
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/245704]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Miao, Xiaopei,Liu, Lu,Wang, Shukuan,et al. Electrochemical synthesis of a ferrocenecarboxylic acid-C-60 composite and its electrocatalysis to hydrogen peroxide[J]. 电化学通讯,2010.
APA	Miao, Xiaopei.,Liu, Lu.,Wang, Shukuan.,Lin, Hong.,Sun, Baoyun.,...&Li, Meixian.(2010).Electrochemical synthesis of a ferrocenecarboxylic acid-C-60 composite and its electrocatalysis to hydrogen peroxide.电化学通讯.
MLA	Miao, Xiaopei,et al."Electrochemical synthesis of a ferrocenecarboxylic acid-C-60 composite and its electrocatalysis to hydrogen peroxide".电化学通讯 (2010).