trans-[Os-III(salen)(CN)(2)](-): A New Paramagnetic Building Block for   the Construction of Molecule-Based Magnetic Materials

doi:10.1021/ic9020178

CORC > 北京大学 > 化学与分子工程学院

	trans-[Os-III(salen)(CN)(2)](-): A New Paramagnetic Building Block for the Construction of Molecule-Based Magnetic Materials
	Guo, Jun-Fang ; Yeung, Wai-Fun ; Lau, Pui-Ha ; Wang, Xiu-Teng ; Gao, Song ; Wong, Wing-Tak ; Chui, Stephen Sin-Yin ; Che, Chi-Ming ; Wong, Wai-Yeung ; Lau, Tai-Chu
刊名	inorganic chemistry
	2010
关键词	BRIDGED BIMETALLIC COMPOUND METAL-CYANIDE CUBES CRYSTAL-STRUCTURE MN-II COORDINATION NETWORKS ORDERING TEMPERATURE TETRAHEDRAL CORNERS SPIN REORIENTATION RE-II ANISOTROPY
DOI	10.1021/ic9020178
英文摘要	A novel dicyanoosmium(III) complex, trans-Ph4P[Os-III(salen)(CN)(2)]center dot CH2Cl2 center dot H2O (1; Ph4P+ = tetraphenylphosphonium cation, salen(2-) =N,N'-ethylenebis(salicylideneaminato) dianion), has been synthesized and structurally characterized. Reactions of 1 with [Cu(Me(3)tacn)(H2O)(2)](ClO4)(2) (Me(3)tacn = 1, 4,7-trimethyl-1, 4,7-triazacyclononane) under different conditions produce the 1-D ferromagnetic zigzag chains [Os(salen)(CN)(2)](2)[Cu(Me(3)tacn)]center dot CH3OH (2) and [Os(salen)(CN)(2)][CU(Me(3)tacn)] - ClO4 (3).; http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000274240700050&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=8e1609b174ce4e31116a60747a720701 ; Chemistry, Inorganic & Nuclear; SCI(E); 20; ARTICLE; 4; 1607-1614; 49
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/244848]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Guo, Jun-Fang,Yeung, Wai-Fun,Lau, Pui-Ha,et al. trans-[Os-III(salen)(CN)(2)](-): A New Paramagnetic Building Block for the Construction of Molecule-Based Magnetic Materials[J]. inorganic chemistry,2010.
APA	Guo, Jun-Fang.,Yeung, Wai-Fun.,Lau, Pui-Ha.,Wang, Xiu-Teng.,Gao, Song.,...&Lau, Tai-Chu.(2010).trans-[Os-III(salen)(CN)(2)](-): A New Paramagnetic Building Block for the Construction of Molecule-Based Magnetic Materials.inorganic chemistry.
MLA	Guo, Jun-Fang,et al."trans-[Os-III(salen)(CN)(2)](-): A New Paramagnetic Building Block for the Construction of Molecule-Based Magnetic Materials".inorganic chemistry (2010).