First Endohedral Metallofullerene-Containing Polymer: Preparation and Characterization of Gd@C-82-Polystyrene | |
Yue, Dongmei ; Bai, Xiaojuan ; Zhao, Shixiong ; Miao, Xiaopei ; Li, Meixian ; Dong, Jinquan ; Ibrahim, Kurash ; Wang, Jiaou ; Zhao, Yuliang ; Yuan, Hui ; Xing, Gengmei ; Sun, Baoyun | |
刊名 | journal of physical chemistry c |
2010 | |
关键词 | ELECTROCHEMICAL PROPERTIES SOLAR-CELLS FULLERENE COPOLYMERS GD-AT-C-82 C-60 LA-AT-C-82 ADDUCTS ANIONS FILMS |
DOI | 10.1021/jp9114578 |
英文摘要 | Metallofullerene-containing copolymers (0.12, 0.20, 0.40, and 0.60 wt % Gd@C-82) were first synthesized via radical bulk copolymerization. The structures and the properties of the new polymers, Gd@C-82-PS, were investigated by GPC, UV-vis spectroscopy, FTIR, C-13 N-MR, CV/DPV, and XPS. The polymerization behavior of the metallofullerene and the properties of the Gd@C-82-PS polymers were different from those of C-60-PS and PS. Gd@C-82 exhibited a stronger radical-scavenging ability than that of hollow fullerenes in the polymerization. Molecular weights and the electron-accepting ability of the polymers were discussed and possible mechanisms of the influences were proposed.; Chemistry, Physical; Nanoscience & Nanotechnology; Materials Science, Multidisciplinary; SCI(E); EI; 7; ARTICLE; 17; 7631-7636; 114 |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://ir.pku.edu.cn/handle/20.500.11897/244474] |
专题 | 化学与分子工程学院 |
推荐引用方式 GB/T 7714 | Yue, Dongmei,Bai, Xiaojuan,Zhao, Shixiong,et al. First Endohedral Metallofullerene-Containing Polymer: Preparation and Characterization of Gd@C-82-Polystyrene[J]. journal of physical chemistry c,2010. |
APA | Yue, Dongmei.,Bai, Xiaojuan.,Zhao, Shixiong.,Miao, Xiaopei.,Li, Meixian.,...&Sun, Baoyun.(2010).First Endohedral Metallofullerene-Containing Polymer: Preparation and Characterization of Gd@C-82-Polystyrene.journal of physical chemistry c. |
MLA | Yue, Dongmei,et al."First Endohedral Metallofullerene-Containing Polymer: Preparation and Characterization of Gd@C-82-Polystyrene".journal of physical chemistry c (2010). |
个性服务 |
查看访问统计 |
相关权益政策 |
暂无数据 |
收藏/分享 |
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。
修改评论