Rh-Catalyzed [7+1] Cycloaddition of Buita-1,3-dienylcyclopropanes and CO   for the Synthesis of Cyclooctadienones

doi:10.1021/ol102700m

CORC > 北京大学 > 化学与分子工程学院

	Rh-Catalyzed [7+1] Cycloaddition of Buita-1,3-dienylcyclopropanes and CO for the Synthesis of Cyclooctadienones
	Yao, Zhong-Ke ; Li, Jianjun ; Yu, Zhi-Xiang
刊名	organic letters
	2011
关键词	VINYLCYCLOPROPANE-CYCLOPENTENE REARRANGEMENT PAUSON-KHAND REACTION 8-MEMBERED RINGS NATURAL-PRODUCTS 3-COMPONENT CYCLOADDITIONS ALKYNES ALKENES CYCLOHEPTATRIENE CONSTRUCTION CARBOCYCLES
DOI	10.1021/ol102700m
英文摘要	Discovering new carbon building blocks is very significant to advance transition-metal-catalyzed cycloadditions for the synthesis of various-sized ring compounds. A new seven-carbon building block from buta-1,3-dienylcyclopropanes (BDCPs) has been developed, showing that, under the catalysis of [Rh(CO)(2)CO2, BDCPs react with CO to give [7 + 1] cycloaddition products, cyclooctadienones. The present (7 + 1) reaction provides an efficient entry to the synthetically challenging eight-membered carbocyclic skeleton, which is present in many natural products of medicinal and biological significance.; Chemistry, Organic; SCI(E); 16; ARTICLE; 1; 134-137; 13
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/243599]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Yao, Zhong-Ke,Li, Jianjun,Yu, Zhi-Xiang. Rh-Catalyzed [7+1] Cycloaddition of Buita-1,3-dienylcyclopropanes and CO for the Synthesis of Cyclooctadienones[J]. organic letters,2011.
APA	Yao, Zhong-Ke,Li, Jianjun,&Yu, Zhi-Xiang.(2011).Rh-Catalyzed [7+1] Cycloaddition of Buita-1,3-dienylcyclopropanes and CO for the Synthesis of Cyclooctadienones.organic letters.
MLA	Yao, Zhong-Ke,et al."Rh-Catalyzed [7+1] Cycloaddition of Buita-1,3-dienylcyclopropanes and CO for the Synthesis of Cyclooctadienones".organic letters (2011).