掺铒的纳米相氟氧化物玻璃陶瓷的多光子红外量子剪裁; Infrared multi-photon quantum cutting of Er-doped nanophase oxyfluoride vitroceramics | |
陈晓波 ; 廖红波 ; 张春林 ; 于春雷 ; 潘伟 ; 胡丽丽 ; 吴正龙 | |
刊名 | 物理学报
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2010 | |
关键词 | 红外量子剪裁现象 太阳能电池 掺铒的纳米相氟氧化物玻璃陶瓷 infrared quantum cutting solar cell Er-doped nanophase oxyfluoride vitroceramics |
英文摘要 | 研究了掺铒的纳米相氟氧化物玻璃陶瓷(Er(3):FOV)的红外量子剪裁现象,测量了红外和可见的Er(3):FOV的荧光光谱.结果发现光激发2H(11/2)能级的4I(13/2)→4I_(15/2)荧光跃迁的近似量子剪裁效率已达约186.28%.; The article reports the infrared quantum cutting phenomenon of the Er-doped nanophase oxyfluoride vitroceramics (Er(3) : FOV). The infrared and visible fluorescence spectra of Er(3) : FOV are measured carefully. It is found that the approximate quantum cutting efficiency of the 1543.0 nm (4)I(13/2) -> (4)I(15/2) fluorescence, when the (2)H(11/2) levels are excited, is about 186. 28%. The relative nonradiative relaxation rate and spontaneous emission rate and energy transfer rate are calculated. The relative energy transfer dynamics is analyzed. It is found that the {(2)H(11/2) -> (4)I(9/2), (4)I(15/2) -> (4)I(13/2)} energy transfer channel, with the rate of 371000 s(-1), is the main reason for (2)H(11/2) energy level to have high quantum cutting efficiency. To our best knowledge, the present article for the first time reports Er(3) : FOV to have an effective three-photon infrared quantum cutting excited by visible light and a four-photon infrared quantum cutting excited by near-violet light.; 国家自然科学基金; http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000280168700106&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=8e1609b174ce4e31116a60747a720701 ; SCI(E); 中文核心期刊要目总览(PKU); 中国科技核心期刊(ISTIC); 中国科学引文数据库(CSCD); 5; 7; 5091-5099; 59 |
语种 | 中文 |
内容类型 | 期刊论文 |
源URL | [http://ir.pku.edu.cn/handle/20.500.11897/243444] ![]() |
专题 | 化学与分子工程学院 |
推荐引用方式 GB/T 7714 | 陈晓波,廖红波,张春林,等. 掺铒的纳米相氟氧化物玻璃陶瓷的多光子红外量子剪裁, Infrared multi-photon quantum cutting of Er-doped nanophase oxyfluoride vitroceramics[J]. 物理学报,2010. |
APA | 陈晓波.,廖红波.,张春林.,于春雷.,潘伟.,...&吴正龙.(2010).掺铒的纳米相氟氧化物玻璃陶瓷的多光子红外量子剪裁.物理学报. |
MLA | 陈晓波,et al."掺铒的纳米相氟氧化物玻璃陶瓷的多光子红外量子剪裁".物理学报 (2010). |
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