Synthesis of Binaphthyl Sulfonimides and Their Application in the   Enantioselective Michael Addition of Ketones to Nitroalkenes

doi:10.1002/ejoc.201000818

CORC > 北京大学 > 化学与分子工程学院

	Synthesis of Binaphthyl Sulfonimides and Their Application in the Enantioselective Michael Addition of Ketones to Nitroalkenes
	Ban, Shurong ; Du, Da-Ming ; Liu, Han ; Yang, Wen
刊名	欧洲有机化学杂志
	2010
关键词	Sulfonamides Organocatalysis Enantioselectivity Michael addition Alkenes CHIRAL SULFONAMIDE LIGANDS TRANSFER HYDROGENATION ATH CROSS-ALDOL REACTIONS PYRROLIDINE SULFONAMIDE CONJUGATE ADDITION DIETHYLZINC ADDITION ASYMMETRIC ADDITION CARBONYL-COMPOUNDS AMINO SULFONAMIDE ALLYLIC ALCOHOLS
DOI	10.1002/ejoc.201000818
英文摘要	Novel types of L-proline-based binaphthyl sulfonimides and sulfonamides were found to be efficient organocatalysts for the asymmetric Michael addition of ketones to nitroalkenes to provide optically active gamma-nitroketone derivatives of synthetic and biological importance. After the fine optimization of solvents, temperature, and additive, good to excellent enantioselectivities and diastereoselectivities (71-96 % ee, up to >99:1 dr) can be achieved.; http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000283102700003&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=8e1609b174ce4e31116a60747a720701 ; Chemistry, Organic; SCI(E); 27; ARTICLE; 27; 5160-5164
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/243317]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Ban, Shurong,Du, Da-Ming,Liu, Han,et al. Synthesis of Binaphthyl Sulfonimides and Their Application in the Enantioselective Michael Addition of Ketones to Nitroalkenes[J]. 欧洲有机化学杂志,2010.
APA	Ban, Shurong,Du, Da-Ming,Liu, Han,&Yang, Wen.(2010).Synthesis of Binaphthyl Sulfonimides and Their Application in the Enantioselective Michael Addition of Ketones to Nitroalkenes.欧洲有机化学杂志.
MLA	Ban, Shurong,et al."Synthesis of Binaphthyl Sulfonimides and Their Application in the Enantioselective Michael Addition of Ketones to Nitroalkenes".欧洲有机化学杂志 (2010).