Direct oxidative arylation via rhodium-catalyzed C-C bond cleavage of   secondary alcohols with arylsilanes

doi:10.1039/c2sc00923d

CORC > 北京大学 > 化学与分子工程学院

	Direct oxidative arylation via rhodium-catalyzed C-C bond cleavage of secondary alcohols with arylsilanes
	Chen, Kang ; Li, Hu ; Li, Yang ; Zhang, Xi-Sha ; Lei, Zhi-Quan ; Shi, Zhang-Jie
刊名	chemical science
	2012
关键词	CARBON-CARBON BOND CROSS-COUPLING REACTIONS QUATERNARY STEREOGENIC CENTERS HOMOALLYL ALCOHOLS ARYLBORONIC ACIDS RETRO-ALLYLATION ARYL HALIDES OXYGEN ATMOSPHERE REGIOSELECTIVE ARYLATION H FUNCTIONALIZATION
DOI	10.1039/c2sc00923d
英文摘要	An unprecedented example of sequential pyridinyl directed C-C cleavage of secondary alcohols/oxidative arylation with arylsilanes via Rh(III) catalysis is reported. Preliminary studies indicated that the arylation initiated from Rh(III)-catalyzed C-C cleavage, and a 5-membered rhodacycle was involved as a key intermediate.; http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000302319000039&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=8e1609b174ce4e31116a60747a720701 ; Chemistry, Multidisciplinary; SCI(E); 34; ARTICLE; 5; 1645-1649; 3
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/236279]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Chen, Kang,Li, Hu,Li, Yang,et al. Direct oxidative arylation via rhodium-catalyzed C-C bond cleavage of secondary alcohols with arylsilanes[J]. chemical science,2012.
APA	Chen, Kang,Li, Hu,Li, Yang,Zhang, Xi-Sha,Lei, Zhi-Quan,&Shi, Zhang-Jie.(2012).Direct oxidative arylation via rhodium-catalyzed C-C bond cleavage of secondary alcohols with arylsilanes.chemical science.
MLA	Chen, Kang,et al."Direct oxidative arylation via rhodium-catalyzed C-C bond cleavage of secondary alcohols with arylsilanes".chemical science (2012).