Reactivity of Seven-Membered Azazirconacycloallenes and Four-Membered Zirconacycles toward Diphenylacetonitrile | |
Zhao, Jing ; Zhang, Shaoguang ; Zhang, Wen-Xiong ; Xi, Zhenfeng | |
刊名 | organometallics
![]() |
2012 | |
关键词 | CARBON BOND FORMATION MEDIATED MULTICOMPONENT REACTIONS METAL-PROMOTED CYCLIZATION ONE-POT SYNTHESIS 5-MEMBERED ZIRCONACYCLOCUMULENES ZIRCONOCENE COMPLEXES MIGRATORY INSERTION EFFICIENT SYNTHESIS VERSATILE BEHAVIOR COUPLING REACTIONS |
DOI | 10.1021/om300949a |
英文摘要 | The reaction of the seven-membered azazirconacycloallene 2 with Ph2CHCN was carried out to yield a zirconocene complex with three fused rings and a keteniminate ligand. Further reactivity toward propargyl bromide or propionyl chloride shows that the keteniminate ligand can be replaced by halogen atoms (Br or Cl). In addition, the reaction of the strained four-membered zirconacycle 1 with Ph2CHCN gives zirconocenes possessing vinyl-imine and keteniminate species.; Chemistry, Inorganic & Nuclear; Chemistry, Organic; SCI(E); EI; 8; ARTICLE; 23; 8370-8374; 31 |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://ir.pku.edu.cn/handle/20.500.11897/228533] ![]() |
专题 | 化学与分子工程学院 |
推荐引用方式 GB/T 7714 | Zhao, Jing,Zhang, Shaoguang,Zhang, Wen-Xiong,et al. Reactivity of Seven-Membered Azazirconacycloallenes and Four-Membered Zirconacycles toward Diphenylacetonitrile[J]. organometallics,2012. |
APA | Zhao, Jing,Zhang, Shaoguang,Zhang, Wen-Xiong,&Xi, Zhenfeng.(2012).Reactivity of Seven-Membered Azazirconacycloallenes and Four-Membered Zirconacycles toward Diphenylacetonitrile.organometallics. |
MLA | Zhao, Jing,et al."Reactivity of Seven-Membered Azazirconacycloallenes and Four-Membered Zirconacycles toward Diphenylacetonitrile".organometallics (2012). |
个性服务 |
查看访问统计 |
相关权益政策 |
暂无数据 |
收藏/分享 |
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。
修改评论