Reactivity of Seven-Membered Azazirconacycloallenes and Four-Membered   Zirconacycles toward Diphenylacetonitrile

doi:10.1021/om300949a

CORC > 北京大学 > 化学与分子工程学院

	Reactivity of Seven-Membered Azazirconacycloallenes and Four-Membered Zirconacycles toward Diphenylacetonitrile
	Zhao, Jing ; Zhang, Shaoguang ; Zhang, Wen-Xiong ; Xi, Zhenfeng
刊名	organometallics
	2012
关键词	CARBON BOND FORMATION MEDIATED MULTICOMPONENT REACTIONS METAL-PROMOTED CYCLIZATION ONE-POT SYNTHESIS 5-MEMBERED ZIRCONACYCLOCUMULENES ZIRCONOCENE COMPLEXES MIGRATORY INSERTION EFFICIENT SYNTHESIS VERSATILE BEHAVIOR COUPLING REACTIONS
DOI	10.1021/om300949a
英文摘要	The reaction of the seven-membered azazirconacycloallene 2 with Ph2CHCN was carried out to yield a zirconocene complex with three fused rings and a keteniminate ligand. Further reactivity toward propargyl bromide or propionyl chloride shows that the keteniminate ligand can be replaced by halogen atoms (Br or Cl). In addition, the reaction of the strained four-membered zirconacycle 1 with Ph2CHCN gives zirconocenes possessing vinyl-imine and keteniminate species.; Chemistry, Inorganic & Nuclear; Chemistry, Organic; SCI(E); EI; 8; ARTICLE; 23; 8370-8374; 31
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/228533]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Zhao, Jing,Zhang, Shaoguang,Zhang, Wen-Xiong,et al. Reactivity of Seven-Membered Azazirconacycloallenes and Four-Membered Zirconacycles toward Diphenylacetonitrile[J]. organometallics,2012.
APA	Zhao, Jing,Zhang, Shaoguang,Zhang, Wen-Xiong,&Xi, Zhenfeng.(2012).Reactivity of Seven-Membered Azazirconacycloallenes and Four-Membered Zirconacycles toward Diphenylacetonitrile.organometallics.
MLA	Zhao, Jing,et al."Reactivity of Seven-Membered Azazirconacycloallenes and Four-Membered Zirconacycles toward Diphenylacetonitrile".organometallics (2012).