Direct Arylation of Primary and Secondary sp(3) C-H Bonds with Diarylhyperiodonium Salts via Pd Catalysis | |
Pan, Fei ; Shen, Peng-Xiang ; Zhang, Li-Sheng ; Wang, Xin ; Shi, Zhang-Jie | |
刊名 | organic letters
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2013 | |
关键词 | UNACTIVATED C(SP(3))-H BONDS CARBON-HYDROGEN BONDS DIARYLIODONIUM SALTS COUPLING REACTIONS INTRAMOLECULAR AMINATION MECHANISTIC INSIGHT C(SP(2))-H BONDS ACID DERIVATIVES PALLADIUM ACTIVATION |
DOI | 10.1021/ol402116a |
英文摘要 | Palladium-catalyzed primary and secondary sp(3) C-H bond arylation is reported. The method using diarylhyperiodonium salts as arylation reagents shows good functional group tolerance and proceeds under mild reaction conditions. The KIE experiments show that the C-H bond activation is the rate-determining step.; Chemistry, Organic; SCI(E); 39; ARTICLE; 18; 4758-4761; 15 |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://ir.pku.edu.cn/handle/20.500.11897/220439] ![]() |
专题 | 化学与分子工程学院 |
推荐引用方式 GB/T 7714 | Pan, Fei,Shen, Peng-Xiang,Zhang, Li-Sheng,et al. Direct Arylation of Primary and Secondary sp(3) C-H Bonds with Diarylhyperiodonium Salts via Pd Catalysis[J]. organic letters,2013. |
APA | Pan, Fei,Shen, Peng-Xiang,Zhang, Li-Sheng,Wang, Xin,&Shi, Zhang-Jie.(2013).Direct Arylation of Primary and Secondary sp(3) C-H Bonds with Diarylhyperiodonium Salts via Pd Catalysis.organic letters. |
MLA | Pan, Fei,et al."Direct Arylation of Primary and Secondary sp(3) C-H Bonds with Diarylhyperiodonium Salts via Pd Catalysis".organic letters (2013). |
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