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A new hybrid zinc phosphite with a pillared layered structure: Synthesis and characterization of [C6N2O2H16][Zn(HPO3)](2)
Wang, Guo-Ming ; Zhang, Xiao ; Li, Jin-Hua ; Wang, Zong-Hua ; Wang, Ying-Xia ; Lin, Jian-Hua
刊名inorganic chemistry communications
2013
关键词Zinc phosphite Hybrid material Hydrothermal synthesis Helical chains Crystal structure 24-RING CHANNELS HYDROTHERMAL SYNTHESIS HELICAL CHAINS FRAMEWORK ZEOLITES
DOI10.1016/j.inoche.2013.08.008
英文摘要By using flexible 1,2-bis(2-aminoethoxy)ethane (BAEOE) as a pillaring ligand, a new inorganic-organic hybrid open-framework zinc phosphite, [C6N2O2H16][Zn(HPO3)](2) (1), has been hydrothermally synthesized and structurally characterized by IR, elemental analysis, thermogravimetric analysis, powder and single-crystal X-ray diffractions. The structure of 1 consists of neutral layers of zinc phosphite which are further pillared through linear BAEOE ligands, generating a 3D framework with unusual (3, 4)-connected dmc topology. The participation of left-handed and right-handed helical chains in the construction of puckered sheet structure with 4.8(2)-net is also noteworthy. (C) 2013 Elsevier B.V. All rights reserved.; Chemistry, Inorganic & Nuclear; SCI(E); 3; ARTICLE; 27-30; 36
语种英语
内容类型期刊论文
源URL[http://ir.pku.edu.cn/handle/20.500.11897/220258]  
专题化学与分子工程学院
推荐引用方式
GB/T 7714
Wang, Guo-Ming,Zhang, Xiao,Li, Jin-Hua,et al. A new hybrid zinc phosphite with a pillared layered structure: Synthesis and characterization of [C6N2O2H16][Zn(HPO3)](2)[J]. inorganic chemistry communications,2013.
APA Wang, Guo-Ming,Zhang, Xiao,Li, Jin-Hua,Wang, Zong-Hua,Wang, Ying-Xia,&Lin, Jian-Hua.(2013).A new hybrid zinc phosphite with a pillared layered structure: Synthesis and characterization of [C6N2O2H16][Zn(HPO3)](2).inorganic chemistry communications.
MLA Wang, Guo-Ming,et al."A new hybrid zinc phosphite with a pillared layered structure: Synthesis and characterization of [C6N2O2H16][Zn(HPO3)](2)".inorganic chemistry communications (2013).
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