Studies on fluorescent species of spiro-indolinonaphthooxazines and their fluorescence spectra | |
Fan, MG ; Liang, YC ; Ming, YF ; Chen, JX ; Ye, T ; Zhang, QY ; Xu, BA ; Jin, S | |
刊名 | research on chemical intermediates
![]() |
1998 | |
关键词 | SPECTROSCOPY SPIROOXAZINES DERIVATIVES RAMAN |
DOI | 10.1163/156856798X00654 |
英文摘要 | Photophysical behavior of spiro[1,3,3-trimethylindolino-2,3'-naphtho[2, 1-b]-1,4-oxazine] (SP1) and spiro[1,3,3,2'-tetramethylindolino-2,3'-naphtho[2, 1-b]-1,4-oxazine] (SP2) were studied. The fluorescent species and their spectra of SP1 and SP2 in polar solvents (acetonitrile and methanol) and non-polar solvent (cyclohexane) were investigated. The fluorescence decay in polar solvents was studied by picosecond time-correlated single photon counting. In most cases, fluorescence decay obeyed triexponential decay kinetics. The major fluorescent species is an excited intermediate which has similar conformation as its precursor ((SP)-S-1*) formed after the bond cleavage between spirocarbon and oxygen in oxazine ring. The effects of molecular structure and solvent polarity on fluorescence spectra and fluorescence decay lifetime were studied.; http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000077958600006&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=8e1609b174ce4e31116a60747a720701 ; Chemistry, Multidisciplinary; SCI(E); 3; REVIEW; 9; 961-971; 24 |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://ir.pku.edu.cn/handle/20.500.11897/218033] ![]() |
专题 | 化学与分子工程学院 |
推荐引用方式 GB/T 7714 | Fan, MG,Liang, YC,Ming, YF,et al. Studies on fluorescent species of spiro-indolinonaphthooxazines and their fluorescence spectra[J]. research on chemical intermediates,1998. |
APA | Fan, MG.,Liang, YC.,Ming, YF.,Chen, JX.,Ye, T.,...&Jin, S.(1998).Studies on fluorescent species of spiro-indolinonaphthooxazines and their fluorescence spectra.research on chemical intermediates. |
MLA | Fan, MG,et al."Studies on fluorescent species of spiro-indolinonaphthooxazines and their fluorescence spectra".research on chemical intermediates (1998). |
个性服务 |
查看访问统计 |
相关权益政策 |
暂无数据 |
收藏/分享 |
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。
修改评论