Photocurrent generation from a self-assembling guest-host LB film of C-60(HOOC(C)under-barHNH(C)under-barHCOOH) and octopentyloxy phthalocyanine | |
Zhao, YL ; Gan, LB ; Zhou, DJ ; Huang, CH ; Jiang, JZ ; Liu, W | |
刊名 | 固体通讯
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1998 | |
关键词 | LIPID BILAYER C-60 FULLERENE DERIVATIVES C60 PYRROLIDINE PORPHYRIN MONOLAYER ESTER C70 |
DOI | 10.1016/S0038-1098(97)10243-5 |
英文摘要 | The photoelectric properties of a guest-host system of C-60(HOOC (C) under bar HNH (C) under bar HCOOH) (C(60)AAD) and 2,3,11,12,20,21,29,30-octopentyloxy phthalocyanine (Pc(OR)(8), R = C5H11) were studied. The evident change of pi-A isotherms and the blue-shift of UV-vis spectra showed that C(60)AAD molecules were incorporated into the cavities of Pc(OR)(8) to form a host-guest Langmuir film at air-water interface. The mixed film could be deposited onto solid substrates with transfer ratio of about 1.05 +/- 0.05 at 15 mN m(-1). The photoelectrochemical investigation of the mixed LB film on ITO electrodes was carried out. Results showed that electrons flow from the ITO through the mixed LB film to the electrolyte. Positive bias voltage, electron acceptor and oxygen were the beneficial factors for energy conversion. The external quantum yield was up to 3.5-4.0% (e/photon) without any bias voltage. (C) 1998 Published by Elsevier Science Ltd.; Physics, Condensed Matter; SCI(E); EI; 9; ARTICLE; 1; 43-48; 106 |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://ir.pku.edu.cn/handle/20.500.11897/217089] ![]() |
专题 | 化学与分子工程学院 |
推荐引用方式 GB/T 7714 | Zhao, YL,Gan, LB,Zhou, DJ,et al. Photocurrent generation from a self-assembling guest-host LB film of C-60(HOOC(C)under-barHNH(C)under-barHCOOH) and octopentyloxy phthalocyanine[J]. 固体通讯,1998. |
APA | Zhao, YL,Gan, LB,Zhou, DJ,Huang, CH,Jiang, JZ,&Liu, W.(1998).Photocurrent generation from a self-assembling guest-host LB film of C-60(HOOC(C)under-barHNH(C)under-barHCOOH) and octopentyloxy phthalocyanine.固体通讯. |
MLA | Zhao, YL,et al."Photocurrent generation from a self-assembling guest-host LB film of C-60(HOOC(C)under-barHNH(C)under-barHCOOH) and octopentyloxy phthalocyanine".固体通讯 (1998). |
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