Crystallographic Snapshots of the Interplay between Reactive Guest and Host Molecules in a Porous Coordination Polymer: Stereochemical Coupling and Feedback Mechanism of Three Photoactive Centers Triggered by UV-Induced Isomerization, Dimerizatio | |
Yang, Shi-Yao ; Deng, Xi-Ling ; Jin, Rui-Fang ; Naumov, Pance ; Panda, Manas K. ; Huang, Rong-Bin ; Zheng, Lan-Sun ; Teo, Boon K. | |
刊名 | journal of the american chemical society
![]() |
2014 | |
关键词 | EXPLORATORY ORGANIC-PHOTOCHEMISTRY SINGLE-CRYSTAL TRANSFORMATION SOLID-STATE 2+2 PHOTODIMERIZATION RADICAL POLYMERIZATION CROSS-LINKING PHOTOPOLYMERIZATION CYCLOADDITION FRAMEWORK NETWORK |
DOI | 10.1021/ja409272p |
英文摘要 | We carried out photopolymerization by [2 + 2] dimerization of a photoreactive guest molecule in the channels of a photoreactive porous coordination polymer. The photoreactions of the guest and two host ligands were monitored by single-crystal X-ray crystallography, providing snapshots of the interplay between the reactive centers. By correlating the structures of these three photocenters, a strong synergism was discovered among three reaction (quasi)equilibria and three types of photochemical reactions (isomerization, dimerization, and polymerization). This result indicates a strong coupling and feedback mechanism among the photocenters moderated by the coordination backbone.; Chemistry, Multidisciplinary; SCI(E); EI; 13; ARTICLE; syyang@xmu.edu.cn; pance.naumov@nyu.edu; 2; 558-561; 136 |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://ir.pku.edu.cn/handle/20.500.11897/216435] ![]() |
专题 | 化学与分子工程学院 |
推荐引用方式 GB/T 7714 | Yang, Shi-Yao,Deng, Xi-Ling,Jin, Rui-Fang,et al. Crystallographic Snapshots of the Interplay between Reactive Guest and Host Molecules in a Porous Coordination Polymer: Stereochemical Coupling and Feedback Mechanism of Three Photoactive Centers Triggered by UV-Induced Isomerization, Dimerizatio[J]. journal of the american chemical society,2014. |
APA | Yang, Shi-Yao.,Deng, Xi-Ling.,Jin, Rui-Fang.,Naumov, Pance.,Panda, Manas K..,...&Teo, Boon K..(2014).Crystallographic Snapshots of the Interplay between Reactive Guest and Host Molecules in a Porous Coordination Polymer: Stereochemical Coupling and Feedback Mechanism of Three Photoactive Centers Triggered by UV-Induced Isomerization, Dimerizatio.journal of the american chemical society. |
MLA | Yang, Shi-Yao,et al."Crystallographic Snapshots of the Interplay between Reactive Guest and Host Molecules in a Porous Coordination Polymer: Stereochemical Coupling and Feedback Mechanism of Three Photoactive Centers Triggered by UV-Induced Isomerization, Dimerizatio".journal of the american chemical society (2014). |
个性服务 |
查看访问统计 |
相关权益政策 |
暂无数据 |
收藏/分享 |
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。
修改评论