Crystallographic Snapshots of the Interplay between Reactive Guest and   Host Molecules in a Porous Coordination Polymer: Stereochemical Coupling   and Feedback Mechanism of Three Photoactive Centers Triggered by   UV-Induced Isomerization, Dimerizatio

doi:10.1021/ja409272p

CORC > 北京大学 > 化学与分子工程学院

	Crystallographic Snapshots of the Interplay between Reactive Guest and Host Molecules in a Porous Coordination Polymer: Stereochemical Coupling and Feedback Mechanism of Three Photoactive Centers Triggered by UV-Induced Isomerization, Dimerizatio
	Yang, Shi-Yao ; Deng, Xi-Ling ; Jin, Rui-Fang ; Naumov, Pance ; Panda, Manas K. ; Huang, Rong-Bin ; Zheng, Lan-Sun ; Teo, Boon K.
刊名	journal of the american chemical society
	2014
关键词	EXPLORATORY ORGANIC-PHOTOCHEMISTRY SINGLE-CRYSTAL TRANSFORMATION SOLID-STATE 2+2 PHOTODIMERIZATION RADICAL POLYMERIZATION CROSS-LINKING PHOTOPOLYMERIZATION CYCLOADDITION FRAMEWORK NETWORK
DOI	10.1021/ja409272p
英文摘要	We carried out photopolymerization by [2 + 2] dimerization of a photoreactive guest molecule in the channels of a photoreactive porous coordination polymer. The photoreactions of the guest and two host ligands were monitored by single-crystal X-ray crystallography, providing snapshots of the interplay between the reactive centers. By correlating the structures of these three photocenters, a strong synergism was discovered among three reaction (quasi)equilibria and three types of photochemical reactions (isomerization, dimerization, and polymerization). This result indicates a strong coupling and feedback mechanism among the photocenters moderated by the coordination backbone.; Chemistry, Multidisciplinary; SCI(E); EI; 13; ARTICLE; syyang@xmu.edu.cn; pance.naumov@nyu.edu; 2; 558-561; 136
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/216435]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Yang, Shi-Yao,Deng, Xi-Ling,Jin, Rui-Fang,et al. Crystallographic Snapshots of the Interplay between Reactive Guest and Host Molecules in a Porous Coordination Polymer: Stereochemical Coupling and Feedback Mechanism of Three Photoactive Centers Triggered by UV-Induced Isomerization, Dimerizatio[J]. journal of the american chemical society,2014.
APA	Yang, Shi-Yao.,Deng, Xi-Ling.,Jin, Rui-Fang.,Naumov, Pance.,Panda, Manas K..,...&Teo, Boon K..(2014).Crystallographic Snapshots of the Interplay between Reactive Guest and Host Molecules in a Porous Coordination Polymer: Stereochemical Coupling and Feedback Mechanism of Three Photoactive Centers Triggered by UV-Induced Isomerization, Dimerizatio.journal of the american chemical society.
MLA	Yang, Shi-Yao,et al."Crystallographic Snapshots of the Interplay between Reactive Guest and Host Molecules in a Porous Coordination Polymer: Stereochemical Coupling and Feedback Mechanism of Three Photoactive Centers Triggered by UV-Induced Isomerization, Dimerizatio".journal of the american chemical society (2014).