Gold nanoparticulate film bound to silicon surface with self-assembled monolayers | |
Wang, J ; Zhu, T ; Song, JQ ; Liu, ZF | |
1998 | |
关键词 | gold nanoparticles sandwiched structure silicon self-assembled monolayers silanization SERS COLLOID MONOLAYERS SPECTROSCOPY ORGANIZATION |
英文摘要 | A simple method for attaching gold nanoparticles to silicon surfaces with self-assembled monolayers (SAMs) is described. Firstly, the silicon wafers were cleaned by a slightly modified RCA method, producing a hydrophilic and smooth surface, as revealed by the small contact angle with water (similar to 5 degrees) and the small RMS value (0.2 nm) for surface roughness given by atomic force microscopy (AFM). Then the wafers were modified with (CH3CH2O)(3)Si-(CH2)(3)-NH2 (APS) by vapor phase deposition. A homogeneous amino group-terminated surface was successfully created as proved by the contact angle with water (40 +/- 2 degrees), the X-ray photoelectron spectroscopy (XPS) results and the AFM images. Gold nanoparticles were quite uniformly scattered over such a surface with a submonolayer coverage through specific interactions with -NH2, leading to a sandwiched structure as Au nanoparticles/APS/Si. Such a silicon-based gold nanoparticulate film was also SERS-active as evidenced by the enhanced Raman scattering from the self-assembled monolayers (SAMs) of an azobenzene-derived thiol adsorbed on thus-prepared substrates. (C) 1998 Elsevier Science S.A. All rights reserved.; Materials Science, Multidisciplinary; Materials Science, Coatings & Films; Physics, Applied; Physics, Condensed Matter; SCI(E); EI; CPCI-S(ISTP); 63 |
语种 | 英语 |
DOI标识 | 10.1016/S0040-6090(98)00719-6 |
内容类型 | 其他 |
源URL | [http://ir.pku.edu.cn/handle/20.500.11897/216148] |
专题 | 化学与分子工程学院 |
推荐引用方式 GB/T 7714 | Wang, J,Zhu, T,Song, JQ,et al. Gold nanoparticulate film bound to silicon surface with self-assembled monolayers. 1998-01-01. |
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