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High-yield preparation of dimetallofullerenes by the improved DC arc discharge method
Lian, YF ; Shi, ZJ ; Zhou, XH ; Gu, ZN ; Xiao, HZ ; Wang, JZ
2000
关键词fullerenes dimetallofullerene endohedral DC arc discharge FULLERENES METALS
英文摘要The soot containing yttrium metallofullerenes was prepared by DC are discharge method under novel conditions including the use of YNi2 alloy, high helium static pressure and high Y:C ratio and extracted by CS2. The extract was enriched by column liquid chromatography on silica gel with a mixed solvent of 85% petroleum ether and 15% xylene, xylene and carbon disulfide as successive eluents. Mass spectra show that dimetallofullerenes with nearly no detectable monometallofullerenes were obtained in bulk quantities. (C) 2000 Elsevier Science Ltd. All rights reserved.; Chemistry, Multidisciplinary; Physics, Condensed Matter; SCI(E); EI; CPCI-S(ISTP); 4
语种英语
DOI标识10.1016/S0022-3697(99)00359-5
内容类型其他
源URL[http://ir.pku.edu.cn/handle/20.500.11897/213110]  
专题化学与分子工程学院
推荐引用方式
GB/T 7714
Lian, YF,Shi, ZJ,Zhou, XH,et al. High-yield preparation of dimetallofullerenes by the improved DC arc discharge method. 2000-01-01.
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