Trifluoromethylthiolation of Diazo Compounds through Copper Carbene   Migratory Insertion

doi:10.1002/ejoc.201402105

CORC > 北京大学 > 化学与分子工程学院

	Trifluoromethylthiolation of Diazo Compounds through Copper Carbene Migratory Insertion
	Wang, Xi ; Zhou, Yujing ; Ji, Guojing ; Wu, Guojiao ; Li, Ming ; Zhang, Yan ; Wang, Jianbo
刊名	欧洲有机化学杂志
	2014
关键词	Diazo compounds Carbenes Fluorine Migratory insertion PALLADIUM-CATALYZED INSERTION HYPERVALENT IODINE REAGENT ARYL FLUOROALKYL SULFIDES ALPHA-FLUORINATED ETHERS FREE-RADICAL ADDITION C-F BOND TRIFLUOROMETHANESULFENYL CHLORIDE NUCLEOPHILIC TRIFLUOROMETHYLATION ELECTROPHILIC TRIFLUOROMETHANESULFANYLATION OXIDATIVE TRIFLUOROMETHYLTHIOLATION
DOI	10.1002/ejoc.201402105
英文摘要	A strategy to introduce the SCF3 group through the Cu-I-promoted reaction of diazo compounds with the nucleophilic AgSCF3 trifluoromethylthiolation reagent was developed. Various diazo compounds were smoothly converted under mild conditions to form the C(sp(3))-SCF3 bond. Mechanistically, migratory insertion of SCF3-bearing Cu carbene intermediates is involved in this transformation.; http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000336377000007&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=8e1609b174ce4e31116a60747a720701 ; Chemistry, Organic; SCI(E); 31; ARTICLE; wangjb@pku.edu.cn; 15; 3093-3096; 2014
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/213042]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Wang, Xi,Zhou, Yujing,Ji, Guojing,et al. Trifluoromethylthiolation of Diazo Compounds through Copper Carbene Migratory Insertion[J]. 欧洲有机化学杂志,2014.
APA	Wang, Xi.,Zhou, Yujing.,Ji, Guojing.,Wu, Guojiao.,Li, Ming.,...&Wang, Jianbo.(2014).Trifluoromethylthiolation of Diazo Compounds through Copper Carbene Migratory Insertion.欧洲有机化学杂志.
MLA	Wang, Xi,et al."Trifluoromethylthiolation of Diazo Compounds through Copper Carbene Migratory Insertion".欧洲有机化学杂志 (2014).