Self-assembly-induced supramolecular hexagonal columnar liquid   crystalline phase using laterally attached nonmesogenic templates

doi:10.1021/ma991768a

CORC > 北京大学 > 化学与分子工程学院

	Self-assembly-induced supramolecular hexagonal columnar liquid crystalline phase using laterally attached nonmesogenic templates
	Tu, HL ; Wan, XH ; Liu, YX ; Chen, XF ; Zhang, D ; Zhou, QF ; Shen, ZH ; Ge, JJ ; Jin, S ; Cheng, SZD
刊名	macromolecules
	2000
关键词	ORDERED MESOPHASE STRUCTURES NEUTRON-SCATTERING EXPERIMENTS TPP POLYETHERS POLYMERS SERIES COPOLYETHERS IDENTIFICATION POLYACRYLATES TRANSITIONS ODD
DOI	10.1021/ma991768a
英文摘要	A novel poly[di(4-heptyl) vinylterephthalate] has been synthesized based upon a free radical polymerization from a newly designed monomer having a nonmesogenic template with two double-swallow-tailed I-heptyl (Y-shaped) groups. The resulting polymer consists of a polyethylene backbone and a 2,5bis-(4-heptyloxycarbonyl)phenyl lateral substitutent on every second carbon atom of the backbone. Although neither the backbone nor the pendent template exhibits liquid crystalline (LC) behavior, they couple together to form a supramolecular hexagonal columnar LC phase on a scale of greater than 1.5 nm in the polymer. Therefore, it is deduced that this supramolecular LC structure is constructed via a cooperative assembly of a helical arrangement of the backbones with the pendent templates.; Polymer Science; SCI(E); EI; 81; ARTICLE; 17; 6315-6320; 33
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/212882]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Tu, HL,Wan, XH,Liu, YX,et al. Self-assembly-induced supramolecular hexagonal columnar liquid crystalline phase using laterally attached nonmesogenic templates[J]. macromolecules,2000.
APA	Tu, HL.,Wan, XH.,Liu, YX.,Chen, XF.,Zhang, D.,...&Cheng, SZD.(2000).Self-assembly-induced supramolecular hexagonal columnar liquid crystalline phase using laterally attached nonmesogenic templates.macromolecules.
MLA	Tu, HL,et al."Self-assembly-induced supramolecular hexagonal columnar liquid crystalline phase using laterally attached nonmesogenic templates".macromolecules (2000).