Cyano-bridged aqua(N,N-dimethylacetamide)(cyanoiron)lanthanides from   samarium, gadolinium, or holmium nitrate and potassium hexacyanoferrate:   Crystal structures and magnetochemistry

doi:10.1002/1522-2675(20010418)84:4&lt;817::AID-HLCA817&gt;3.0.CO;2-U

CORC > 北京大学 > 化学与分子工程学院

	Cyano-bridged aqua(N,N-dimethylacetamide)(cyanoiron)lanthanides from samarium, gadolinium, or holmium nitrate and potassium hexacyanoferrate: Crystal structures and magnetochemistry
	Yan, B ; Chen, Z
刊名	瑞士化学会志
	2001
关键词	CHROMIUM(III) NICKEL(II) CYANIDE LANTHANIDE ION COMPLEXES MOLECULAR-BASED MAGNETS ONE-DIMENSIONAL ARRAYS STATE ENERGY-TRANSFER SILVER DICYANIDES TRANSITION-METALS LIGANDS CU HEXAFLUOROACETYLACETONATO
DOI	10.1002/1522-2675(20010418)84:4<817::AID-HLCA817>3.0.CO;2-U
英文摘要	Three cyano-bridged aqua(N.N-dimcthylacrtamide)(cyanoiron)lanthanide complexes were synthesized by the reaction of K(3)Fe(CN)(6). Ln(NO(3))(3). 6H(2)O (Ln = Sm, Gd, Ho), and N.N-dimethylacetamide (DMA). The obtained complexes 1-3 exhibit different coordination geometries and crystal structures. The polymeric {[Sm(DMA)(2)(H(2)O)(4)Fr(CN)(6). 5H(2)O}(n) ([SmFe](n): 1) has a one-dimensional chain structure with approximately parallel trans-positioned bridging CN ligands between the Sm- and Fe-atoms. [(Gd(DMA)(3)(H(2)O)(4))(2)Fe(CN)(6)] [Fe(CN)(6)]. 3H(2)O (Gd(2)Fe: 2) is an isolated trinuclear Gd(l)-Fe-Gd(2) complex with two approximately perpendicular cis-positioned bridging CN ligands between the two Gd-atoms and the Fe-atom. [Ho(DMA)(3-)(H(2)O)(3)Fe(CN)(6)] . 3H(2)O (HoFe: 3) adopts a single dinuclear crystal structure with only one bridging CN between the Ho- and Fe-atom. Magnetochemistry experiments establish weak antiferromagnetic interactions between Gd(III) land Ho(III)) and Fe(III) atoms. Especially the [SmFe],, complex 1 exhibits long-range magnetic ordering. T(c) = 3.5 K, and a stronger coercive force. H(c) = 1400 Oe.; Chemistry, Multidisciplinary; SCI(E); EI; 18; ARTICLE; 4; 817-829; 84
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/211470]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Yan, B,Chen, Z. Cyano-bridged aqua(N,N-dimethylacetamide)(cyanoiron)lanthanides from samarium, gadolinium, or holmium nitrate and potassium hexacyanoferrate: Crystal structures and magnetochemistry[J]. 瑞士化学会志,2001.
APA	Yan, B,&Chen, Z.(2001).Cyano-bridged aqua(N,N-dimethylacetamide)(cyanoiron)lanthanides from samarium, gadolinium, or holmium nitrate and potassium hexacyanoferrate: Crystal structures and magnetochemistry.瑞士化学会志.
MLA	Yan, B,et al."Cyano-bridged aqua(N,N-dimethylacetamide)(cyanoiron)lanthanides from samarium, gadolinium, or holmium nitrate and potassium hexacyanoferrate: Crystal structures and magnetochemistry".瑞士化学会志 (2001).