Photoelectric behavior of nanocrystalline TiO2 electrode with a novel   terpyridyl ruthenium complex

doi:10.1016/S0927-0248(01)00085-X

CORC > 北京大学 > 化学与分子工程学院

	Photoelectric behavior of nanocrystalline TiO2 electrode with a novel terpyridyl ruthenium complex
	Wang, ZS ; Huang, CH ; Huang, YY ; Zhang, BW ; Xie, PH ; Hou, YJ ; Ibrahim, K ; Qian, HJ ; Liu, FQ
刊名	solar energy materials and solar cells
	2002
关键词	Gratzel cell black dye TiO2 nanocrystalline TiO2 dye sensitized solar cell terpyridyl ruthenium dyes photoelectrochemical solar cells CHARGE-TRANSFER FILMS CONVERSION LIGHT PHOTOSENSITIZATION SENSITIZATION AGGREGATION EFFICIENCY
DOI	10.1016/S0927-0248(01)00085-X
英文摘要	The photoelectric behavior of a black dye, tris (isothiocyanato)-[N-(2,2':6', 2"-terpyridine-4-(4-carbuxylic acid) phenyl)] ruthenium (II) complex, was examined under different conditions. The dye was adsorbed on nanocrystalline TiO2 surface strongly and generated incident monochromatic photon-to-current conversion efficiency (IPCE) of about 90% at maximum absorption wavelength and greater than 20% in the near-IR region. A sandwich-type solar cell fabricated by this dye-sensitized nanocrystalline TiO2 film generated 6.1 mA cm(-2) of short-circuit photocurrent, 0.58 V of open-circuit photovoltage and 2.9% of overall yield under irradiation of white light (78,0 mW cm(-2)) from a Xe lamp. Since the title dye shows better photoresponse than the N3 dye in the near-IR region, it would be a promising panchromatic sensitizer after optimization. (C) 2002 Elsevier Science B.V. All rights reserved.; Energy & Fuels; Materials Science, Multidisciplinary; Physics, Applied; SCI(E); EI; 30; ARTICLE; 2; 261-271; 71
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/210807]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Wang, ZS,Huang, CH,Huang, YY,et al. Photoelectric behavior of nanocrystalline TiO2 electrode with a novel terpyridyl ruthenium complex[J]. solar energy materials and solar cells,2002.
APA	Wang, ZS.,Huang, CH.,Huang, YY.,Zhang, BW.,Xie, PH.,...&Liu, FQ.(2002).Photoelectric behavior of nanocrystalline TiO2 electrode with a novel terpyridyl ruthenium complex.solar energy materials and solar cells.
MLA	Wang, ZS,et al."Photoelectric behavior of nanocrystalline TiO2 electrode with a novel terpyridyl ruthenium complex".solar energy materials and solar cells (2002).