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	Palladium complexes of side-chain liquid crystal polymers with T-shaped two-dimensional mesogenic units
	Zhang, SY ; Deng, G ; Li, ZF ; Cao, SK ; Zhou, QF
刊名	先进技术聚合物
	2002
关键词	liquid crystal polymers palladium complex T-shaped two-dimensional mesogens TRANSITION-METAL COMPLEXES SERIES MESOMORPHISM POLYSILOXANE
DOI	10.1002/pat.98
英文摘要	A series of liquid crystal polymers (LCPs) with T-shaped two-dimensional mesogenic units were synthesized via solution polycondensation. The LCPs were used as ligand polymers to coordinate with palladium dichloride, by which a series of polymeric palladium complexes were prepared. The liquid crystalline behaviors of the compounds ere characterized using differential scanning calorimetry, polarized microscopy and X-ray diffraction. The entire palladium complexes went to liquid crystal phase when heated to their melting temperature (T-m), and a threaded texture was observed. The melting point of all the complexes changes regularly with the increase of the end alkoxy group length and the flexible spacer unit in the ligand polymer. It is worth noting that some of the complexes without end substituent groups in the ligand polymer were also found to show liquid crystal behaviors, which would be a subject for further investigation. Copyright (C) 2001 John Wiley Sons, Ltd.; Polymer Science; SCI(E); EI; 5; ARTICLE; 1; 1-5; 13
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/210277]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Zhang, SY,Deng, G,Li, ZF,et al. Palladium complexes of side-chain liquid crystal polymers with T-shaped two-dimensional mesogenic units[J]. 先进技术聚合物,2002.
APA	Zhang, SY,Deng, G,Li, ZF,Cao, SK,&Zhou, QF.(2002).Palladium complexes of side-chain liquid crystal polymers with T-shaped two-dimensional mesogenic units.先进技术聚合物.
MLA	Zhang, SY,et al."Palladium complexes of side-chain liquid crystal polymers with T-shaped two-dimensional mesogenic units".先进技术聚合物 (2002).

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