A novel Cu(II)-W(v) bimetallic assembly magnet   {[Cu(en)(2)](3)[W(CN)(8)](2)center dot H2O} infinity (en =   ethylenediamine) with cube-like W8Cu12 units from a coordinated anion   template self-assembly reaction

doi:10.1039/b108791f

CORC > 北京大学 > 化学与分子工程学院

	A novel Cu(II)-W(v) bimetallic assembly magnet {[Cu(en)(2)](3)[W(CN)(8)](2)center dot H2O} infinity (en = ethylenediamine) with cube-like W8Cu12 units from a coordinated anion template self-assembly reaction
	Li, DF ; Gao, S ; Zheng, LM ; Sun, WY ; Okamura, T ; Ueyama, N ; Tang, WX
刊名	new journal of chemistry
	2002
关键词	MOLECULAR-BASED MAGNETS LADDER CHAIN STRUCTURE HIGH-SPIN MOLECULES CRYSTAL-STRUCTURE BUILDING-BLOCKS GROUND-STATE PRUSSIAN-BLUE CYANIDE COMPLEX MAGNETIZATION
DOI	10.1039/b108791f
英文摘要	A novel molecular-based magnet of three-dimensional (3-D) cyanide-bridged bimetallic assembly, {[Cu(en)(2)](3)[W(CN)(8)](2).H2O}(infinity) (1), where en = ethylenediamine, was synthesized and structurally characterized. The assembly has a three-dimensional network structure extended by three kinds of Cu-II-NC-W-nu-CN-Cu-II linkages with very long axial Cu-N-cyanide interactions due to Jahn Teller effects. The network is based on a W8Cu12 cube-like unit with eight [W(CN)(8)](3-) anions at the corners of the distorted cube and twelve [Cu(en)(2)](2+) cations at the middle of the edges, in which a coordination anion [W(CN)(8)](3-) acting as template = guest is capsulated in the cavity of the W8Cu12 cube. Magnetic studies reveal that the complex displays 3-D ferromagnetic ordering over the lattice below the Curie temperature at around 2 K.; http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000174726600022&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=8e1609b174ce4e31116a60747a720701 ; Chemistry, Multidisciplinary; SCI(E); 47; ARTICLE; 4; 485-489; 26
语种	英语
内容类型	期刊论文
源URL	[http://ir.pku.edu.cn/handle/20.500.11897/210238]
专题	化学与分子工程学院
推荐引用方式 GB/T 7714	Li, DF,Gao, S,Zheng, LM,et al. A novel Cu(II)-W(v) bimetallic assembly magnet {[Cu(en)(2)](3)[W(CN)(8)](2)center dot H2O} infinity (en = ethylenediamine) with cube-like W8Cu12 units from a coordinated anion template self-assembly reaction[J]. new journal of chemistry,2002.
APA	Li, DF.,Gao, S.,Zheng, LM.,Sun, WY.,Okamura, T.,...&Tang, WX.(2002).A novel Cu(II)-W(v) bimetallic assembly magnet {[Cu(en)(2)](3)[W(CN)(8)](2)center dot H2O} infinity (en = ethylenediamine) with cube-like W8Cu12 units from a coordinated anion template self-assembly reaction.new journal of chemistry.
MLA	Li, DF,et al."A novel Cu(II)-W(v) bimetallic assembly magnet {[Cu(en)(2)](3)[W(CN)(8)](2)center dot H2O} infinity (en = ethylenediamine) with cube-like W8Cu12 units from a coordinated anion template self-assembly reaction".new journal of chemistry (2002).